李俊華

1992.07-2001.12 中國原子能科學研究院

2002.01-2003.11 清華大學環境科學與工程系 博士后

2003.12-2007.12 清華大學環境科學與工程系（副研究員）

2007.12-2011.01 清華大學環境科學與工程系（研究員）

2008.03-2009.06 密西根大學工學院 訪問教授

2011.01-至今 清華大學環境學院（研究員）

2017.04.11-至今 煙氣多污染物控制技術與裝備國家工程實驗室主任

中國能源學會 理事

中國環境科學學會大氣環境分會 理事

中國氣象學會大氣化學委員會 委員

中國電機工程協會電力環境保護委員會委員

中國電力企業聯合會節能環保分會 專家

環保部火電污染防治專業委員會委員

國家氣象學會大氣化學委員會委員

燃煤煙氣脫硝技術創新戰略聯盟專家委員會秘書長等

研究領域

大氣污染化學及控制化學研究

固定源燃煤煙氣脫硫脫硝除汞新技術原理和應用開發

汽車尾氣凈化催化劑的研究及應用開發

室內空氣污染凈化技術

長期致力於大氣污染控制化學及關鍵控制技術的研究，多年來在燃煤煙氣脫硝、機動車排放控制等大氣污染控制領域做出了重要貢獻。

先後主持和參加10餘項國家863高科技研究計劃、國家自然科學基金以及國內外企業合作項目；

在環境和化學類期刊上發表文章160餘篇、編寫專著3部、發明專利18項。

研究概況

大氣污染控制化學，國家傑出青年科學基金，2014-2017；

多介質複合污染與控制化學，國家自然科學基金，2013-2015；

低溫碳基催化劑協同控制NOx和CVOCs的機理研究，國家自然科學基金，2015-2018；

大氣無機污染組分在近實際大氣條件下對二次細粒子的貢獻, 中科院戰略性先導科技專項子課題（XDB05010102）2014-2017；

Selective Catalytic Reduction of Nitric Oxide at low temperature, Nitto Denko Technical Corporation, Japan, 2015-2016;

Understanding the Materials and Catalysis of New Generation Copper Zeolite Urea-SCR for Vehicle NOx Control, URP Project, Ford Motor Company, USA, 2011-2016；

工業鍋爐/爐窯煙氣中低溫催化凈化氮氧化物技術及示範，國家863課題，2012-2015；

燃煤電站多污染物綜合控制技術研究與示範，國家863課題，2013-2015

面向國VI的重型柴油車后處理集成技術研究，國家863課題，2013-2015；

板式脫硝催化劑在電廠低負荷運行的適應性研究，大唐南京環保科技公司，2014-1015；

新型改性氧化鈰催化劑低溫脫硝協同脫汞機理研究，國家自然科學基金，2013-2015；

燃煤電廠煙氣低溫脫硝關鍵技術研發，國電江蘇龍源催化劑有限公司，2013-2015；

著作

煙氣催化脫硝關鍵技術研發與應用，科學出版社，2015.

環境催化：原理及應用，科學出版社, 科學出版社，2008.

Book chapter co-authored by Dr. Li, “Effect of Highly Concentrated Dry (NH4)2SO4 Seed Aerosols on Ozone and Secondary Organic Aerosol Formation in Aromatic Hydrocarbon/NOx Photooxidation Systems,” in Atmospheric Aerosols, 2009

Book chapter co-authored by Dr. Li, “Effects of inorganic seeds on secondary organic aerosol (SOA) formation,” in Atmospheric Aerosols: Regional Characteristics—Chemistry and Physics, 2012

Book chapter co-authored by Dr. Li, “Catalytic CO2 reforming of methane over perovskite noble metals,” in Advanced Materials Research: Progress in Environmental Science and Engineering, Parts 1-5, 2012

論文

1.B Bai, J.H. Li*, J Hao.1D-MnO2, 2D-MnO2 and 3D-MnO2 for low-temperature oxidation of ethanol. Applied Catalysis B: Environmental, 2015, 164, 241-250. 2.Y Peng, J Li*, W Si, J Luo, Y Wang, J Fu, X Li, J Crittenden, J Hao. Deactivation and regeneration of a commercial SCR catalyst: Comparison with alkali metals and arsenic. Applied Catalysis B: Environmental, 2015, 168: 195-202. 3.Y Peng, J.H. Li*, W Si, J Luo, Q Dai, X Luo, X Liu, J Hao. New Insight into Deactivation of Commercial SCR Catalyst by Arsenic: an Experiment and DFT Study. Environmental science & technology, 2014, 48 (23): 13895–13900. 4.L Ma, Y Cheng, G Cavataio, RW McCabe, L Fu, J Li*. In situ DRIFTS and temperature-programmed technology study on NH3-SCR of NO over Cu-SSZ-13 and Cu-SAPO-34 catalysts. Applied Catalysis B: Environmental, 2014, 156, 428-437. 5.B.Y., J.H. Li*. Positive Effects of K+ Ions on Three-Dimensional Mesoporous Ag/Co3O4 Catalyst for HCHO Oxidation. ACS Catal., 2014, 4 (8): 2753–2762. 6.H.Z. Chang, J.H. Li* et. al. A novel mechanism for poisoning of metal oxide SCR catalysts: base-acid explanation correlated with redox properties. Chem. Commun., 2014, 50: 10031-10034. 7.Z.M. Liu, S.X. Zhang, J.H. Li. Novel V2O5-CeO2/TiO2 catalyst with low vanadium loading for the selective catalytic reduction of NOx by NH3. Appl. Catal. B- Environ., 2014, 158: 11-19. 8.S.J. Yang, S.C. Xiong, Y. Liao, F.H. Qi, X. Xiao, Y. Peng, Y.W. Fu, W.P. Shan, J.H. Li. Mechanism of N2O Formation during the Low-Temperature Selective Catalytic Reduction of NO with NH3 over Mn-Fe Spinel. Environ. Sci. Technol. 2014, 48: 10354-10362. 9.Peng Y; Wang CZ; Li JH. Structure-activity relationship of VOx/CeO2 nanorod for NO removal with ammonia. Appl. Catal. B-Environ. 2014, 144: 538-546.

2.10.L. Ma; Y.S. Cheng; C. Giovanni; R.W. McCabe; L.X. Fu; J.H. Li. In situ DRIFTS and temperature-programmed technology study on NH3-SCR of NOx over Cu-SSZ-13 and Cu-SAPO-34 catalysts Appl. Catal. B-Environ., 2014, 156, 428-437. 11.Liu ZM; Zhang SX; Li JH; Ma LL. Promoting effect of MoO3 on the NOx reduction by NH3 over CeO2/TiO2 catalyst studied with in situ DRIFTS. Appl. Catal. B-Environ. 2014, 144: 90-95. 12.Ma, L; Wang, DS; Li, JH; Bai, BY; Fu, LX; Li, YD. Ag/CeO2 nanospheres: Efficient catalysts for formaldehyde oxidation. Appl. Catal. B-Environ., 2014, 148, 36-43. 13.Peng, Y; Li, JH; Huang, X; Li, X; Su, WK; Sun, XX; Wang, DZ; Hao, JM. Deactivation Mechanism of Potassium on the V2O5/CeO2 Catalysts for SCR Reaction: Acidity, Reducibility and Adsorbed-NOx. Environ. Sci. Technol. 2014, 48: 4515-4520 14.B.Y. Bai, H. Arandiyan, J.H. Li. Comparison of the performance for oxidation of formaldehyde on nano-Co3O4, 2D-Co3O4, and 3D-Co3O4 catalysts. Appl. Catal. B-Environ. 2013, 142, 677-683. 15.H. Arandiyan, H.X. Dai, J.G. Deng, Y.X. Liu, B.Y. Bai, Y. Wang, X.W. Li, S.H. Xie, J.H. Li. Three-dimensionally ordered macroporous La0.6Sr0.4MnO3 with high surface areas: Active catalysts for the combustion of methane. J. Catal. 2013, 307, 327-339. 16.H. Arandiyan, H.X. Dai, J.G. Deng, Y. Wang, S.H. Xie, J.H. Li. Dual-templating synthesis of three-dimensionally ordered macroporous La0.6Sr0.4MnO3-supported Ag nanoparticles: controllable alignments and super performance for the catalytic combustion of methane. Chem. Commun. 2013, 49, (91), 10748-10750. 17.H.Z. Chang, X.Y. Chen, J.H. Li, L. Ma, C.Z. Wang, C.X. Liu, J.W. Schwank, J.M. Hao. Improvement of Activity and SO2 Tolerance of Sn-Modified MnOx-CeO2 Catalysts for NH3-SCR at Low Temperatures. Environ. Sci. Technol. 2013, 47, (10), 5294-5301. 18.H.Z. Chang, M.T. Jong, C.Z. Wang, R.Y. Rui, Y. Du, J.H. LiM. Hao. Design Strategies for P-Containing Fuels Adaptable CeO2-MoO3 Catalysts for DeNO(x): Significance of Phosphorus Resistance and N-2 Selectivity. Environ. Sci. Technol. 2013, 47, (20), 11692-11699.

19.Z.M. Liu, Y. Yi, J.H. Li, S.I. Woo, Wang, B. Y., X.Z. Cao, Z.X. Li. A superior catalyst with dual redox cycles for the selective reduction of NOx by ammonia. Chem. Commun. 2013, 49, (70), 7726-7728.

20.Y. Peng, K.H, J.H. Li. Identification of the active sites on CeO2-WO3 catalysts for SCR of NOx with NH3: An in situ IR and Raman spectroscopy study. Appl. Catal. B-Environ. 2013, 140, 483-492.

21.Y. Peng, C.X. Liu, X.Y. Zhang, J.H. Li. The effect of SiO2 on a novel CeO2-WO3/TiO2 catalyst for the selective catalytic reduction of NO with NH3. Appl. Catal. B-Environ. 2013, 140, 276-282.

22.Y. Peng, R.Y. Rui, X.Y. Zhang, J.H. Li. The relationship between structure and activity of MoO3-CeO2 catalysts for NO removal: influences of acidity and reducibility. Chem. Commun. 2013, 49, (55), 6215-6217.

23.R.Y. Rui, X. Gao, K.F. Cen, J.H. Li. Relationship between structure and performance of a novel cerium-niobium binary oxide catalyst for selective catalytic reduction of NO with NH3. Appl. Catal. B-Environ. 2013, 142, 290-297.

24.Peng Y., Li J., Shi W., Xu J., Hao J. Design strategies for development of SCR catalyst: Improvement of alkali poisoning resistance and novel regeneration method. Environ. Sci. Technol., 2012, 46(22): 12623-12629.

25.Liu Caixia, Chen Liang, Li Junhua, Ma Lei, Arandiyan Hamidreza, Du Yu, Xu Jiayu, Hao, Jiming. Enhancement of Activity and Sulfur Resistance of CeO2 Supported on TiO2-SiO2 for the Selective Catalytic Reduction of NO by NH3. Environ. Sci. Technol., 2012, 46: 6182-6189.

26.Lei Ma, Junhua Li, Yisun Cheng, Christine K. Lambert, and Lixin Fu. Propene Poisoning on Three Typical Fe-zeolites for SCR of NOx with NH3: From Mechanism Study to Coating Modified Architecture. Environ. Sci. Technol., 2012, 46 (3): 1747–1754.

27.Yue Peng, Junhua Li, Liang Chen, Jinghuan Chen, Jian Han, He Zhang, and Wei Han. Alkali Metal Poisoning of a CeO2–WO3 Catalyst Used in the Selective Catalytic Reduction of NOx with NH3: an Experimental and Theoretical Study. Environ. Sci. Technol., 2012, 46 (5): 2864–2869.

28.Yang Shijian, Li Junhua, Wang Chizhong, Chen Jinghuan, Ma Lei, Chang Huazheng, Chen Liang, Peng Yue, Yan Naiqiang,. Fe-Ti spinel for the selective catalytic reduction of NO with NH3: Mechanism and structure-activity relationship. Applied Catalysis B: Environm, 2012, 117: 73-80.

29.Liu Zhiming, Li Junhua, Woo, Seong Ihl. Recent advances in the selective catalytic reduction of NOx by hydrogen in the presence of oxygen, Energy & Environmental Science, 2012, 5(10): 8799-8814.

30.Huang, Zhiwei, Gu Xiao, Cao Qingqing, Hu, Pingping, Hao, Jiming, Li, Junhua, Tang Xingfu. Catalytically Active Single-Atom Sites Fabricated from Silver Particles. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 2012, 51: 4198-4203.

31.Jinghuan Chen, Wenbo Shi, Xueying Zhang, Hamidreza Arandiyan, Dongfang Li, and Junhua Li. Roles of Li+ and Zr4+ Cations in the Catalytic Performances of Co1–xMxCr2O4 (M = Li, Zr; x = 0–0.2) for Methane Combustion. Environ. Sci. Technol., 2011, 45 (19): 8491–8497.

32.Yang Shijian, Wang Chizhong, Li Junhua, Yan Naiqiang, Ma Lei, Chang Huazheng. Low temperature selective catalytic reduction of NO with NH(3) over Mn-Fe spinel: Performance, mechanism and kinetic study. Applied Catalysis B: Environmental, 2011, 110: 71-80.

33.Jinghuan Chen, Wenbo Shi, Shijian Yang, Hamidreza Arandiyan, and Junhua Li. Distinguished Roles with Various Vanadium Loadings Of CoCr2–xVxO4 (x = 0–0.20) for Methane Combustion. J. Phys. Chem. C, 2011, 115 (35): 17400–17408.

34.Lei Ma, Junhua Li, Rui Ke, Lixin Fu. Catalytic Performance, Characterization, and Mechanism Study of Fe2(SO4)3/TiO2 Catalyst for Selective Catalytic Reduction of NOx by Ammonia. Journal of Physical Chemistry C 2011, 115 (15), 7603-7612.

35.Liang Chen, Junhua Li, and Maofa Ge. DRIFT Study on Cerium？Tungsten/Titiania Catalyst for Selective Catalytic Reduction of NOx with NH3. Environ. Sci. Technol., 2010, 44 (24), 9590–9596.

36.Li J H, Wang R H, Hao J M. Role of lattice oxygen and lewis acid on ethanol oxidation over OMS-2 catalyst. J. Phys. Chem. C, 2010, 144(23), 10544-10550.

37.Wang R H, Li J H. Effects of precursor and sulfation on OMS-2 catalyst for oxidation of ethanol and acetaldehyde at low temperatures. Environ. Sci. Technol., 2010, 44 (11), 4282–4287.

38.Junhua Li, Ronghai Zhu, Yisun Cheng, Christine K. Lambert, Ralph T. Yang Mechanism of propene poisoning on Fe-ZSM-5 for selective catalytic reduction of NOx with ammonia, Environmental Science and Technology, Environ. Sci. Technol., 2010, 44 (5) 1799–1805.

39.Tang, XF; Li, JH; Sun L, Hao, JM. Origination of N2O from NO reduction by NH3 over beta-MnO2 and alpha-Mn2O3. Appl. Catal. B: Environm., 2010，99, 156-162

40.Liang Chen, Junhua Li*, Mafa Ge, Promotional Effect of Ce-doped V2O5-WO3/TiO2 with Low Vanadium Loadings for Selective Catalytic Reduction of NOx by NH3. J. Phys. Chem. C, 2009, 113, 21177–21184.

41.Junhua Li, Woo Huang Goh, Xuechang Yang, Ralph T. Yang. Non-thermal Plasma-Assisted Catalytic NOx Storage over Pt/Ba/Al2O3 at low temperatures. Applied Catalysis B: Environmental, 2009，Vol.90, 360-367.

42.Guohua Jing, Junhua Li, Dong Yang, Jiming Hao. Promotional Mechanism of Tungstation on Selective Catalytic Reduction of NOx by Methane over In/WO3/ZrO2. Applied Catalysis B: Environmental, 2009，Vol.91, 123-134.

43.Junhua Li, Xi Liang, Shicheng Xu, Jiming Hao. Manganese-doped cobalt oxides on methane combustion at low temperature. Applied Catalysis B Environmental, Applied Catalysis B: Environmental, 2009，Vol.90, 307-312.

專利

1)李俊華，黃旭，彭悅，關立軍，王子騰，郝吉明. 一種用於低溫煙氣脫硝的環型SCR反應器，ZL 201420614789.5;

2)李俊華，黃旭，彭悅，關立軍，王子騰，郝吉明. 一種用於低溫煙氣脫硝的箱式側流反應器，ZL 201420614774.9;

3)李俊華，陳景歡，李冬芳，郝吉明。用於天然氣尾氣甲烷凈化的分子篩催化劑製備及應用。專利號：ZL 201210078645.8;

4)李俊華，陳景歡，李冬芳，郝吉明。一種用於甲烷低溫氧化反應的整體式催化劑及其製備，專利號：ZL 201210080375.4;

5)李俊華，常化振，郝吉明. 一種新型氧化鈰脫硝催化劑及其製備方法。中國, ZL 2012105728143;

6)李俊華，馬磊，傅立新，郝吉明. Fe和Cu複合分子篩催化劑的製備方法及應用。中國, ZL 201210532005.X;

7)李俊華，陳景歡，李冬芳，郝吉明。用於天然氣尾氣甲烷凈化的分子篩催化劑製備及應用。中國, ZL 201210078645.8;

8)李俊華，陳景歡，李冬芳，郝吉明。一種用於甲烷低溫氧化反應的整體式催化劑及其製備。中國, ZL 201210080375.4;

9)李冬芳，陳景歡，郝吉明。負載型複合Co3O4/CeO2-Al2O3/堇青石催化劑，製備方法。中國, ZL 201210082622.4;

10)李俊華，汪俊，陳亮，許嘉鈺，郝吉明。一種V2O5-WO3/TiO2催化劑鹼金屬中毒后的再生方法。中國,ZL 201110071623.4;

11)李俊華，陳亮，葛茂發，許嘉鈺，烏吉丹，汪俊. 一種以鈦硅複合氧化物為載體的鈰基脫硝催化劑及其製備和應用。中國,ZL 201110024615.4;

12)李俊華，陳亮，葛茂發, 郝吉明. 一種中低溫抗硫型鈰鎢複合氧化物脫硝催化劑。中國,ZL 201110027215.9;

13)李俊華，馬磊，李東玲，傅立新. 銅基分子篩催化劑及其製備方法. ZL 201010511126.7;

14)李俊華，常化振，郝吉明. 一種錳基低溫脫硝催化劑及其製備方法.,ZL201010223099.3;

15)段雷，萬奇，賀克斌，陳亮，李俊華. 一種用於燃煤電廠煙氣單質汞氧化的催化劑及其製備方法。中國,ZL 201010176293.0;

16)李俊華，陳亮，郝吉明. 一種低釩脫硝催化劑及其製備方法和應用，國家發明專利。中國, ZL 200910087773.7;

17)李俊華, 王仁虎, 郝吉明. 八面體錳氧化物分子篩催化劑的製備方法。中國,ZL 200910024337.5;

18)李俊華, 馬磊, 郝吉明, 傅立新. 一種Fe分子篩複合催化劑及其製備方法。中國,ZL 200910024336.0;

19)李俊華, 王仁虎, 郝吉明. 一種負載金屬氧化物的分子篩催化劑及其製備方法。中國,ZL 200910024338.X;

20)李俊華，陳亮，郝吉明. 一種鈰基脫硝催化劑及其製備方法。中國,ZL 200910219534.2;

21)康守方，李俊華，傅立新. 稀燃汽油車尾氣排放NOx凈化催化劑製備方法。中國,ZL 0510086550.0;

22)李俊華，郝吉明，傅立新, 朱天樂。富氧條件下在雙床組合催化劑體系中還原NO的方法。中國,ZL 03102406.8;

23)朱天樂，郝吉明，傅立新，李俊華. 一種室內空氣凈化方法。中國,ZL 03100288.9;

24)朱天樂，郝吉明，傅立新，王建昕，李俊華，劉志明，崔翔宇. 一種貧燃型車用發動機尾氣催化凈化方法。中國,ZL 03140511.8.

主要課程

大氣化學和物理（研究生）

專業實習（留學生）

作為我國大氣污染控制研究領域的青年專家，李俊華教授針對中國大氣污染的實際情況，對固定源燃煤煙氣及稀燃機動車尾氣中NOx控制基礎理論和關鍵控制技術原理，溫室氣體甲烷和揮發性有機污染物的催化氧化機制進行了系統研究，並在NOx污染控制技術研究方面走在國際前沿，研究成果得到國內外學術界的高度評價。其主要研究成果在燃煤電廠、稀燃汽車、工業爐窯等多種行業實現了NOx和VOCs減排的工業化應用，大大提升了我國環保產業在核心技術方面的國際競爭力，成功使我國火電廠NOx排放標準控制在全球最嚴格的排放限值內。

2021年6月，入選中國工程院2021年院士增選進入第二輪評審候選人名單。