趙蓓

1995年蘇州大學有機化學專業畢業，獲碩士學位，期間赴南開大學做訪問學者1年。同年留校工作，2006年獲有機化學博士學位。

2011年獲得江蘇政府留學基金資助，赴新加坡訪學。

稀土金屬有機化合物的合成、結構及其催化性質，導向有機合成的金屬有機化學，不對稱合成等。

主要貢獻

主持國家自然科學基金2項，江蘇省高校自然科學研究項目1項，參加2項國家自然科學基金項目和1項省部級項目。在國內外化學核心期刊如Green Chem., Org. Lett., Org. Chem. Front., Dalton Trans., Organometallics, Catal. Sci. Technol., J. Polym. Sci. Polym. Chem.等發表論文數十篇，授權發明專利4項。

主要論文：

1. Intermolecular addition of alcohols to carbodiimides catalyzed by rare-earth metal amides

L. J. Hu,C. R. Lu, B. Zhao*, Y. M. Yao

Org. Chem. Front., 2018, DOI: 10.1039/C7QO00991G

2. An amidato divalent ytterbium cluster: synthesis and molecular structure, its reactivity to carbodiimides and application in the guanylation reaction

C. Gong, H. Ding, C. R. Lu, B. Zhao*, Y. M. Yao

Dalton Trans., 2017,46, 6031-6038.

3.Efficient asymmetric hydrophosphonylation of unsaturated amides catalyzed by rare-earth metal amides [(MeSi)N]RE(m-Cl)Li(THF)with phenoxy-functionalized chiral prolinols

Z. H. Fei, C. Zeng, C. R. Lu, B. Zhao*, Y. M. Yao

RSC Adv.2017,7, 19306-19311.

4. Synthesis and characterization of bridged bis(amidato) rare earth metal amides and their applications in C–N bond formation reactions

B. Zhao,* Y. Xiao, D. Yuan, C. R. Lu, Y. M. Yao

Dalton Trans.2016,45, 3880-3887.

5. Asymmetric michael addition of malonates to unsaturated ketones catalyzed by rare earth metal complexes bearing phenoxy functionalized chiral diphenylprolinolate ligands

Q. Q. Qian, W. G. Zhu, C. R. Lu, B. Zhao*, Y. M. Yao

Tetrahedron: Asy.2016,27, 911-917.

6.Synthesis and characterization of amidato divalent lanthanide complexes and their use in forming 2,4-quinazolidinones from COand 2-aminobenzonitriles

Q. Y.Wang,C. R.Lu, B.Zhao*,Y. M.Yao

Eur. J. Org. Chem., 2016, 2555-2559.

7. Carboxylation of terminal alkynes with COcatalyzed by bis(amidate) rare-earth metal amides

H. Cheng, B. Zhao,* Y. M. Yao, C. R. Lu

Green Chem., 2015,17, 1675-1682.

8.Highly enantioselective epoxidation ofα,β-unsaturated ketones catalyzed by rare-earth amides [(MeSi)N]RE(μ-Cl)Li(THF)with phenoxy-functionalized chiral prolinols

C. Zeng, D. Yuan, B. Zhao,* Y. M. Yao

Org. Lett., 2015,17, 2242-2245.

9. Synthesis and characterization of bis(amidate) rare-earth metal amides and their application in catalytic addition of amines to carbodiimides

H. Cheng, Y. Xiao, C. R. Lu, B. Zhao,* Y. R. Wang, Y. M. Yao

New J. Chem.,2015,39, 7667-7671.

10. Synthesis and characterization of rare-earth metal complexes supported by a new pentadentate Schiff base and their application in heteroselective polymerization of rac-lactide

Y. Cui, W. K. Gu, Y. R. Wang,* B. Zhao,* Y. M. Yao, Q. Shen

Catal. Sci. Technol.,2015,5, 3302-3312.

11.Synthesis and characterization of rare-earth metal guanidinates stabilized by amine-bridged bis(phenolate) ligands and their application in the controlled polymerization ofrac-lactide andrac-b-butyrolactone

T. H. Zeng, Q. Q. Qian, B. Zhao,* D. Yuan, Y. M. Yao*, Q. Shen

RSC Adv.2015,5, 53161-53171.

12.C-N bond formation reaction catalyzed by Organo-rare-earth metal amides (Invited Review)

Y. Xiao, Q. Y. Wang, B. Zhao*, Y. M. Yao*

Chin. J. Org. Chem.2015,35, 1598-1614.

13.Asymmetric epoxidation of unsaturated ketones catalyzed by heterobimetallic rare-earth-lithium complexes bearing phenoxy functionalized chiral diphenylprolinolate ligand

Q. Q. Qian, Y. F. Tan, B. Zhao,* T. Feng, Q. Shen, Y. M. Yao*

Org. Lett., 2014,16,4516-4519.

14.Synthesis and characterization of amidate rare-earth metal amides and their catalyticactivities toward hydrophosphonylation of aldehydes and unactivated ketones

L. Zhao, H. Ding, B. Zhao,* C. R. Lu, Y. M. Yao

Polyhedron, 2014,83, 50-59.

15. Asymmetric hetero-Diels-Alder reaction of Danishefsky’s dienes witha-carbonyl esters catalyzed by an indium(III)-PyBox complex

B. Zhao, T. P. Loh

Org. Lett.,2013,15, 2914-2917.

16.Unexpected C−H bond activation promoted by bimetallic lanthanide amido complexes bearing a META-phenylene bridged bis(β-diketiminate) ligand

S. Sun, Q. Sun, B. Zhao*, Y. Zhang, Q. Shen, Y. M. Yao*

Organometallics, 2013,32, 1876-1881.

17.Bimetallic lanthanide amido complexes as highly active initiators for the ring-opening polymerization of lactides

S.Sun, K. Nie, Y. F. Tan, B. Zhao*, Y. Zhang, Q. Shen, Y. M. Yao*

Dalton Trans., 2013,42, 2870-2878.

18.Synthesis and structural diversity of lanthanide amidate complexes and their catalytic activities for the ring-opening polymerization ofrac-lactide

X.L. Hu, C. R. Lu, B. Wu, H. Ding, B. Zhao*, Y. M. Yao*, Q. Shen

J. Organomet. Chem., 2013,732, 92-101.

19.Addition of terminal alkynes to aromatic nitriles catalyzed by divalent lnathanide amides supported by amidates: synthesis of ynones

H. Ding, C. R. Lu, X. L. Hu, B. Zhao*, B. Wu, Y. M. Yao*

Synlett, 2013,24, 1269-1274.

20.Ring-opening polymerization of trimethylenecarbonate by the bridged diphenoxo ytterbium (II) complex

B. Zhao, X. L. Hu, C. R. Lu

J. Appl. Polym. Sci.,2011,120, 2693.

21.One-pot synthesis of salicylanilides by direct amide bond formation from salicyclic acid under microwave irradiation

C. R. Lu, B. Zhao*, Y. P. Jiang, H. Ding, S. Yang

Syn. Commun.,2011,41, 1257.

22.Ring-opening polymerization of trimethylenecarbonate and its copolymerization withe-caprolactone by lanthanide (II) aryloxide complexes

B. Zhao, C. R. Lu, Q. Shen

J. Appl. Polym. Sci., 2007,106, 1383.

23. Metallomacrocycle complexes of lanthanides with bridged amide ligands: syntheses and molecular structures of [{μ-p-(MeSiN)CH}YbCl(THF)]and [{μ-p-(MeSiN)CH}Nd(μ-Cl)(THF)]·2PhMe

B. Zhao, H. H. Li, Q. Shen, Y. Zhang, Y. M. Yao, C. R. Lu

Organometallics,2006,25, 1824.

24.Polymerization of N-phenyl maleimide by lanthanide complexes

B. Zhao, Y. R. Wang, C. R. Lu, Q. Shen, M. Y. Deng

J.Polym. Sci. Polym. Chem.,2005,43, 3966.