徐小平

蘇州大學副教授

徐小平,男,蘇州大學材化部副教授。擔任本科生《有機化學》,《有機化學實驗》,《化學與健康》等課程的教學任務。研究領域為金屬配合物的合成及其反應性能,催化劑導向及介質調控的高效及高選擇性反應。

學術經歷


主持江蘇省省屬高校自然科學基礎研究項目、江蘇省有機合成重點實驗室開放課題各一項。以第一作者和通訊作者的身份在國內外核心化學期刊如Inorg. Chem,J. Polym. Sci., Part A: Polym. Chem.,Adv. Synth. Catal., Org. Biomol. Chem.等發表論文四十餘篇,參與的項目“稀土金屬催化劑及其在可生物降解高分子材料合成中的應用”獲2009年度蘇州市科學技術進步獎一等獎,江蘇省科學技術進步獎二等獎。主要參與的項目“功能性有機分子的合成、性質及應用研究”獲2010年中國石油與化學工業聯合會科技進步二等獎、2011年蘇州市科技進步二等獎(排名第二)。

主講課程

擔任本科生《有機化學》,《有機化學實驗》,《化學與健康》等課程的教學任務。

研究方向

金屬配合物的合成及其反應性能,催化劑導向及介質調控的高效及高選擇性反應。

主要貢獻


論文及參編著作
1.Synthesis, Characterization of Carbon-Bridged Biphenolate Lanthanide Complexes and Their Catalytic Activity for the Diels-Alder Reactions,X. P. Xu,M. T. Ma, Y. M. Yao, Y. Zhang, Q. Shen,Eur. J. Inorg. Chem.,2005, 676.
2.Homopolymerization of Cyclic Esters Initiated by Lanthanide Isopropoxides Supported by 2,2’-Ethylene-bis(4,6-di-tert- butylphenolate) Ligands,X. P. Xu,Y. M. Yao, M. Y. Hu, Y. Zhang, Q. Shen,J. Polym. Sci.: Part A: Polym. Chem.,2006,44, 4409.
3.Synthesis, Reactivity and Structural Characterization of Sodium and Ytterbium Complexes Containing New Imidazolidine-Bridged Bis(phenolato) Ligands,X. P. Xu,Y. M. Yao, Y. Zhang, Q. Shen,Inorg. Chem.2007,46, 3743.
4.Controlled Synthesis, Characterization and Reactivity of Neutral and Anionic lanthanide Amides Supported by Methylene-linked Bis(phenolate) Ligands,X. P. Xu,Y. M. Yao, Y. Zhang, Q. Shen,Inorg. Chem.2007, 46, 9379.
5.Cerium ammonium nitrate: an efficient catalyst for carbon-carbon bond formation from ferrocenyl alcohol substrate,X. P. Xu,R. Jiang, X. G. Zhou, Y. Liu, S. J. Ji,Tetrahedron2009,65, 877.
6.Bismuth(III)-promoted C3-ferrocenylalkylation of indoles, R. Jiang, T. Chen, H. Y. Li, G. Chen,X. P. Xu*,S. J. Ji*,Synlett2009, 2815.
7.Nano Iron Oxide as a Recyclable Catalyst for the Intramolecular C-N Cross-Coupling Reaction under Ligand Free conditions: the One-Pot Synthesis of 1,4-Dihydroquinoline Derivatives, X. J. Wu, R. Jiang, B. Wu, X. M. Su,X. P. Xu*,S. J. Ji*,Adv. Synth. Catal.2009,351, 3150.
8.Ferric(III) Nitrate: An efficient Catalyst for the Regioselective Friedel-Crafts Reactions of Indoles andtert-Enamides in Water, R. Jiang, X. J. Wu, X. Zhu,X. P. Xu*, S. J. Ji*,Eur. J. Org. Chem.2010, 5946.
9.A Convergent Construction of 1,4-Dihydropyridine Scaffold Containing Indole Fragment, T. Chen,X. P. Xu*, H. F. Liu, S. J. Ji*,Tetrahedron2011, 67, 5469.
10.Direct Alkylation of Indoles and Amines bytert-Enamides: Facile Access to Pharmaceutically active 2-pyrrolidinone Analogues, R. Jiang, H. Y. Xu,X. P. Xu*, X. Q. Chu, S. J. Ji*,Org. Biomol. Chem.2011, 9, 5659.
11.紀順俊、史達清等,《現代有機合成新技術》,化學工業出版社, 2009.
12.黃志斌、路建美主編《綜合化學實驗》,南京大學出版社 2009.