張弛

南開大學元素有機化學國家重點實驗室固定研究人員。

2001年至2003年在美國Stanford大學化學系做博士后，研究模擬酶。

2003年任南開大學教授、2005年任博士生導師。

研究方向

有機合成化學，目前主要從事的研究領域：(1)有機高價碘試劑（hypervalent iodine chemistry）新反應性的研究，設計合成新的有機高價碘試劑並探索它們的新反應性；(2)C-H鍵的官能團化；（3）天然產物的全合成。

論文

● ● “Recyclable Hypervalent Iodine(III) Reagent Iodosodilactone as an Efficient Coupling Reagent for Direct Esterification, Amidation, and Peptide Coupling” J. Tian, W.-C. Gao, D.-M. Zhou, C. Zhang*, Org. Lett. 2012, 14, 3020-3023.

2. “A Mild and Efficient Direct a-Amination of b-Dicarbonyl Compounds Using Iodosobenzene and p-Toluenesulfonamide Catalyzed by Perchlorate Zinc Hexahydrate” J. Yu, S.-S. Liu, J. Cui, X.-S. Hou, C. Zhang*, Org. Lett. 2012, 14, 832-835.

3. “A Dramatic Solvent Effect on One-Pot Synthesis of Substituted Ureas Directly from Primary Alcohols Using the Combined Reagent of Iodobenzene Dichloride and Sodium Azide in Ethyl Acetate” C. Zhang*, W.-K. Wang, T. He, Synthesis 2012, Accepted (invited).

4. “Enantioselective a-tosyloxylation of ketones catalyzed by spirobiindane scaffold-based chiral iodoarenes” J. Yu, J. Cui, X.-S. Hou, S.-S. Liu, W.-C. Gao, S. Jiang, J. Tian, C. Zhang*, Tetrahedron: Asymmetry. 2011, 22, 2039-2055.

徠5. “Design, Synthesis, Structure, and Dehydrogenation Reactivity of a Water-Soluble o-Iodoxybenzoic Acid Derivative Bearing a Trimethylammonium Group” L.-Q. Cui, Z.-L. Dong, K. Liu, C. Zhang*, Org. Lett. 2011, 13, 6488-6491.

6. “Effective oxidation of benzylic and alkane C-H bonds catalyzed by sodium o-iodobenzenesulfonate with Oxone as a terminal oxidant under phase-transfer conditions” L.-Q. Cui, K. Liu, C. Zhang*, Org. Biomol. Chem. 2011, 9, 2258-2265.

7. “One-Pot Synthesis of Symmetrical 1,3-Diarylureas or Substituted Benzamides Directly from Benzylic Primary Alcohols and Effective Oxidation of Secondary Alcohols to Ketones Using Phenyliodine Diacetate in Combination with Sodium Azide” X.-Q. Li, W.-K. Wang, Y.-X. Han, C. Zhang*, Adv. Synth. Catal. 2010, 352, 2588-2598.

8. “Various a-Oxygen Functionalizations of b-Dicarbonyl Compounds Mediated by the Hypervalent Iodine(III) Reagent p-Iodotoluene Difluoride with Different Oxygen-Containing Nucleophiles” J. Yu, J. Tian, C. Zhang*, Adv. Synth. Catal. 2010, 352, 531-546.

9. “One-Pot Synthesis of Carbamoyl Azides Directly from Primary Alcohols and Oxidation of Secondary Alcohols to Ketones Using Iodobenzene Dichloride in Combination with Sodium Azide” X.-Q. Li, W.-K. Wang, C. Zhang*, Adv. Synth. Catal. 2009, 351, 2342-2350.

10. “A Safe, Convenient and Efficient One-Pot Synthesis of -Chloroketone Acetals Directly from Ketones Using Iodobenzene Dichloride” J. Yu, C. Zhang*, Synthesis 2009, 2324-2328.

11. “An Environmentally Benign TEMPO-Catalyzed Efficient Alcohol Oxidation System with a Recyclable Hypervalent Iodine(III) Reagent and Its Facile Preparation” X.-Q. Li, C. Zhang*, Synthesis 2009, 1163-1169.

12. “Iodobenzene dichloride in combination with sodium azide for the effective synthesis of carbamoyl azides from aldehydes” X.-Q. Li, X.-F. Zhao, C. Zhang*, Synthesis 2008, 2589-2593.

13. “Iodobenzene dichloride as a stoichiometric oxidant For the conversion of alcohols into carbonyl compounds; Two facile methods for its preparation” X.-F. Zhao, C. Zhang*, Synthesis 2007, 551-557.

14. “A Simple and Effective Synthesis of Benzolactones and Benzolactams Via Benzylic Oxidation of Cyclic Benzyl Ethers and N-protected Cyclic Benzyl Amines Using Sodium Chlorite as an Oxidant without a Catalyst” A.-R. Song, J. Yu, C. Zhang*, Synthesis 2012, Accepted.

15. “A Simple and Effective Method for a-Hydroxylation of b-Dicarbonyl Compounds Using Oxone as an Oxidant without a Catalyst” J. Yu, J. Cui, C. Zhang*, Eur. J. Org. Chem. 2010, 7020-7026.

16. “A Simple Method for Epoxidation of Olefins Using Sodium Chlorite as an Oxidant without a Catalyst” X.-L. Geng, Z. Wang, X.-Q. Li, C. Zhang*, J. Org. Chem. 2005, 70, 9610-9613.