趙玉軍

能源化工催化

綠色多相催化工藝

催化加氫/加氫脫氧

合成氣制乙二醇/乙醇催化劑

催化劑工程

講授課程:

石油煉製工藝學

長期在綠色化學與能源化工催化領域從事研究工作。在多相固體催化劑的表界面調控、催化反應機理、構效關係與協同作用機制、催化劑設計及其工程放大等方面取得了一系列重要的理論和應用成果。重點負責天津大學合成氣制乙二醇/乙醇關鍵技術開發與工程放大研發任務，完成了關鍵催化劑的研製以及工程化放大工作，形成了天津大學自主知識產權的合成氣制乙二醇/乙醇成套關鍵技術並在工程中成功應用。目前在AIChE J.、Chem. Commun.、Chem. Eng. Sci.、Chem. Eng. J.、Ind. Eng. Chem. Res.、Appl. Catal.A等高水平期刊發表論文40餘篇。申請中國專利15餘項、美國等國外專利9項，其中授權中國專利12項、授權美國等國外專利3項。

ACS Catalysis, AIChE Journal, Chemical Engineering Science, Industrial &Engineering Chemistry Research, ChemCatChem, Applied Catalysis A,Catalysis Science Technology, Catalysis Communications, Chinese Journal of Catalysis, Journal of Chemical Technology & Biotechnology, Chemselect, Journal of Industrial and Engineering Chemistry 等學術期刊審稿人

承擔項目

1)國家自然科學基金：草酸酯加氫銅基催化劑結構與價態調控

2)中石油科技創新基金：草酸酯加氫制乙二醇銅基規整結構催化劑研究

3)天津市自然基金重點項目：草酸酯加氫制乙二醇銅基規整結構催化劑關鍵技術

4)中國博士后基金：草酸二甲酯加氫制乙二醇整體催化劑研究

5)天津市濱海新區自主創新重大平台項目：煤制乙二醇工程中心平台建設

6) 中石油勘探研究院：CO/N開關型表面活性劑開發

參加項目

1）國家高技術研究發展計劃（863計劃）：煤制乙醇、低碳醇技術-煤制燃料乙醇

2）國家重大研究計劃-多相反應過程中的介尺度機制及調控：合成氣制乙二醇催化劑結構調控與反應-擴散耦合機制

3)貴州鑫新集團：碳一化學與化工技術開發

4)惠生工程：能源化工聯合研發

5)棗礦集團：煤制乙二醇中試及工業化示範工程

6)黑龍江華本能源：合成氣制乙二醇萬噸級工程放大

7)神華集團：CO2吸附增強的耐硫甲烷化催化劑和工藝過程

1) Yujun Zhao*, Bin Shan, Yue Wang, Jiahua Zhou, Shengping Wang and Xinbin Ma, An Effective CuZn-SiO2 Bimetallic Catalyst Prepared by Hydrolysis Precipitation Method for the Hydrogenation of Methyl Acetate to Ethanol, Ind Eng Chem Res. DOI: 10.1021/acs.iecr.7b05391 ( Cover story)

2) Yujun Zhao, Ziyuan Guo, Haojie Zhang, Bo Peng, Yuxi Xu, Yue Wang, Jian Zhang, Yan Xu, Shengping Wang, and Xinbin Ma*, Hydrogenation of Diesters on Copper Catalyst Anchored on Ordered Hierarchically Porous Silica, J. Catal. 357(2018)223-237.

3) Peng Jin*, Chang Liu, Ying Li, Lanlan Li*, Yujun Zhao*, Th@C76. Computational characterization of larger actinide endohedral fullerene, International Journal of Quantum Chemistry. DOI: 10.1002/qua.25501, 2017.

4) Peng Jin*, Chang Liu, Muqing Chen, Qinghua Hou, Lanlan Li* and Yujun Zhao*, Comparative study on the N-heterocyclic carbene adducts of Ih-C60, D5h-C70 and Sc3N@Ih-C80, Phys. Chem. Chem. Phys., 19(2017) 17598-17606.

5) Yujun Zhao, Ziyuan Guo, Haojie Zhang, Yuxi Xu, Yue Wang, Jian Zhang, Yan Xu*, Shengping Wang, and Xinbin Ma*, Ordered mesoporous CuZn/HPS catalysts for the chemoselective hydrogenation of dimethyl adipate to 1, 6-hexanediol, Chem Lett, 46 (2017) 1079-1082.

6) Jia He, Yujun Zhao*, Yue Wang, Junhu Wang, Jian Zheng, Hanlei Zhang, Guangwen Zhou, Chongmin Wang, Shengping Wang and Xinbin Ma, A FeC nanocatalyst for the preferential synthesis of ethanol via dimethyl oxalate hydrogenation, Chem. Commun., 53 (2017) 5376-5379. ( Cover story).

7) Yujun Zhao*, Yaqing Zhang, Yue Wang, Jian Zhang, Yan Xu, Shengping Wang, Xinbin Ma, Structure evolution of mesoporous silica supported copper catalyst for dimethyl oxalate hydrogenation, Applied Catalysis A: General 539 (2017) 59-69.

8) Yue Wang, Junyu Liao, Jian Zhang, Shengping Wang, Yujun Zhao* and Xinbin Ma, Hydrogenation of methyl acetate to ethanol by Cu/ZnO catalyst encapsulated in SBA-15, AIChE Journal, 63 (2017) 2839–2849.

9) Yujun Zhao, Siming Li, Yue Wang, Bin Shan, Jian Zhang, Shengping Wang, Xinbin Ma*, Efficient tuning of surface copper species of Cu/SiO2 catalyst for hydrogenation of dimethyl oxalate to ethylene glycol, Chemical Engineering Journal, 2017, 113, 759–768.

10) Yue Wang, Yujun Zhao, Jing Lv and Xinbin Ma*, Facile Synthesis of Cu@CeO2 and Its Catalytic Behavior for the Hydrogenation of Methyl Acetate to Ethanol, ChemCatChem, 2017, DOI: 10.1002/cctc.201700111.

11) Wei Zhou, Yujun Zhao, Yue Wang, Shengping Wang and Xinbin Ma, Glycerol Hydrogenolysis to 1,3-Propanediol on Pt/WO3/ZrO2: Hydrogen Spillover Facilitated by Pt(111) Formation, ChemCatChem, DOI: 10.1002/cctc.201600981

12) G.Z. Xu, J. Zhang *, S.P. Wang, Y.J. Zhao*, X.B. Ma, Effect of thermal pretreatment on the surface structure of PtSn/SiO2 catalyst and its performance in acetic acid hydrogenation, Frontiers of Chemical Science and Engineering, 2016, 10(3):417-424

13) G.Z. Xu, J. Zhang *, S.P. Wang, Y.J. Zhao*, X.B. Ma, A well fabricated PtSn/SiO catalyst with enhanced synergy between Pt and Sn for acetic acid hydrogenation to ethanol, RSC Advances, 2016, 6, 51005 – 51013

14) M.Y. Ouyang, Y. Wang, J.Zhang, Y.J. Zhao*, S.P. Wang and X.B. Ma, Three dimensional Ag/KCC-1 catalyst with hierarchical fibrous framework for the hydrogenation of dimethyl oxalate, RSC Advances, 2016, 6, 12788 – 12791

15) Y.J. Zhao, S. Zhao, Y. Geng, Y.L Shen, H.R. Yue, J. Lv, S.P. Wang and X.B. Ma*, Ni-containing Cu/SiO2 catalyst for the chemoselective synthesis of ethanol via hydrogenation of dimethyl oxalate, Catalysis Today, 2016, 276: 28-35

16) Y.B. Song, J. Zhang, J. Lv, Y.J. Zhao*, X.B. Ma, Hydrogenation of Dimethyl Oxalate over Copper based Catalysts: Acid-Base Properties and Reaction Paths, Ind Eng Chem Res. 2015; 54(10): 9699−9707.

17) S.M. Li, Y. Wang, J. Zhang, S.P. Wang, Y. Xu, Y.J. Zhao*, X. B. Ma, Kinetics Study of Hydrogenation of Dimethyl Oxalate over Cu/SiO2Catalyst, Ind Eng Chem Res. 2015;54(4):1243-1250.

18) Y. Xu, Q. Chen, Y.J. Zhao*, J. Lv, Z.H. Li, X.B. Ma*, Autocatalytic Kinetic Study of Dimethyl Oxalate Consecutive Hydrolysis. Ind Eng Chem Res. 2014;53(11):4207-4214.

19) S.P. Wang, S.S. Fan, Y.J. Zhao, L.J. Fan, S.Y. Liu, X.B Ma. Carbonation Condition and Modeling Studies of Calcium-Based Sorbent in the Fixed-Bed Reactor. Ind Eng Chem Res. 2014. doi10.1021/ie500789g

20) Y.L. Meng, T. Wang, S. Chen, Y.J. Zhao, X.B. Ma, J.L. Gong. Selective oxidation of methanol to dimethoxymethane on V2O5–MoO3/γ-Al2O3 catalysts. Appl. Catal. B, 2014; 160-161(0):161-172.

21) J.L. Gong, H.R. Yue, Y.J. Zhao, S. Zhao, L. Zhao, J. Lv, S.P. Wang, X.B. Ma, Synthesis of Ethanol via Syngas on Cu/SiO2 Catalysts with Balanced Cu0–Cu+ Sites, Journal of the American Chemical Society, 134 (2012) 13922-13925.

22) H.R. Yue, Y.J Zhao, S. Zhao, B. Wang, X.B. Ma, J.L. Gong, A copper-phyllosilicate core-sheath nanoreactor for carbon–oxygen hydrogenolysis reactions, Nat Commun, 4 (2013). 2339 doi10.1038/ncomms3339.

23) H.R. Yue, Y.J. Zhao, L. Zhao, J. Lv, S.P. Wang, J.L. Gong, X.B. Ma, Hydrogenation of dimethyl oxalate to ethylene glycol on a Cu/SiO2/cordierite monolithic catalyst: Enhanced internal mass transfer and stability, AIChE Journal, 58 (2012) 2798-2809.

24) H.R. Yue, Y.J. Zhao, X.B. Ma, J.L. Gong, Ethylene glycol: properties, synthesis, and applications, Chem. Soc. Rev., 41 (2012) 4218-4244.

25) L. Zhao, Y.J. Zhao, S.P. Wang, H.R. Yue, B. Wang, J. Lv, X.B. Ma, Hydrogenation of Dimethyl Oxalate Using Extruded Cu/SiO2 Catalysts: Mechanical Strength and Catalytic Performance, Ind Eng Chem Res, 51 (2012) 13935-13943.

26) S. Zhao, H.R. Yue, Y.J. Zhao, B. Wang, Y.C. Geng, J. Lv, S.P. Wang, J.L. Gong, X.B. Ma, Chemoselective synthesis of ethanol via hydrogenation of dimethyl oxalate on Cu/SiO2: Enhanced stability with boron dopant, J Catal, 297 (2013) 142-150.

27) X.B. Ma, H.W. Chi, H.R. Yue, Y.J. Zhao, Y. Xu, J. Lv, S.P. Wang, J.L. Gong, Hydrogenation of dimethyl oxalate to ethylene glycol over mesoporous Cu-MCM-41 catalysts, AIChE Journal, 59 (2013) 2530-2539.

28) S.P. Wang, H.L. Shen, S.S. Fan, Y.J. Zhao, X.B. Ma, J.L. Gong, Enhanced CO2 adsorption capacity and stability using CaO-based adsorbents treated by hydration, AIChE Journal, 59 (2013) 3587-3593.

29) Y. Xu, W.J. Dou, Y.J. Zhao, G.X. Huang, X.B. Ma, Kinetics Study for Ion-Exchange-Resin Catalyzed Hydrolysis of Methyl Glycolate, Ind Eng Chem Res, 51 (2012) 11653-11658.

30) S.P. Wang, L. Zhao, W. Wang, Y.J. Zhao, G. Zhang, X.B. Ma, J.L. Gong, Morphology control of ceria nanocrystals for catalytic conversion of CO2 with methanol, Nanoscale, 5 (2013) 5582-5588.

31) Y.Y. Dong, S.Y. Huang, S.P. Wang, Y.J Zhao, J.L. Gong, X.B. Ma, Synthesis of Dimethyl Carbonate through Vapor-Phase Carbonylation Catalyzed by Pd-Doped Zeolites: Interaction of Lewis Acidic Sites and Pd Species, Chemcatchem, 5 (2013) 2174-2177.

32) S. Chen, Y.L. Meng, Y.J. Zhao, X.B. Ma, J.L. Gong, Selective Oxidation of Methanol to Dimethoxymethane over Mesoporous Al-P-V-O Catalysts, AIChE Journal, 59 (2013) 2587-2593.

33) S.P. Wang, X. Zhang, Y.J. Zhao, Y.D. Ge, J. Lv, B. Wang, X.B. Ma, Pd-Fe/α-Al2O3/cordierite monolithic catalysts for the synthesis of dimethyl oxalate: effects of calcination and structure, Front. Chem. Sci. Eng., 6 (2012) 259-269.

34) Y.D. Ge, Y.Y. Dong, S.P. Wang, Y.J. Zhao, J. Lv, X.B. Ma, Influence of crystalline phase of Li-Al-O oxides on the activity of Wacker-type catalysts in dimethyl carbonate synthesis, Front. Chem. Sci. Eng., 6 (2012) 415-422.

35) X.C. Gao, Y.J. Zhao, S.P. Wang, Y.L. Yin, B. Wang, X.B. Ma, A Pd-Fe/alpha-Al2O3/cordierite monolithic catalyst for CO coupling to oxalate, Chemical Engineering Science, 66 (2011) 3513-3522.

36) Y.J. Zhao, J. Zhou, J.G. Zhang, D.Y. Li, S.D. Wang, Selective hydrogenation of benzene to cyclohexene on a Ru/Al2O3/cordierite monolithic catalyst: Effect of mass transfer on the catalytic performance, Ind Eng Chem Res, 47 (2008) 4641-4647.

37) Y.J. Zhao, J. Zhou, J.G. Zhang, S.D. Wang, Liquid-phase selective hydrogenation of benzene to cyclohexene on Ru/Al2O3-ZrO2/cordierite monolithic catalysts, J Mol Catal a-Chem, 309 (2009) 35-39.

38) Y.J. Zhao, J. Zhou, J.G. Zhang, S.D. Wang, Preparation and Characterization of Ru/Al2O3/Cordierite Monolithic Catalysts for Selective Hydrogenation of Benzene to Cyclohexene, Catal Lett, 131 (2009) 597-605.

39) Y.J. Zhao, J. Zhou, J.G. Zhang, S.D. Wang, Monolithic Ru-based catalyst for selective hydrogenation of benzene to cyclohexene, Catal Commun, 9 (2008) 459-464.

40) J.G. Zhang, D.F. Li, Y.J. Zhao, Q.D. Kong, S.D. Wang, A Pd/Al2O3/cordierite monolithic catalyst for hydrogenation of 2-ethylanthraquinone, Catal Commun, 9 (2008) 2565-2569.