葉保輝

1994年畢業於中山大學，獲博士學位：

1994年10月至1997年10月在香港科技大學作博士后，

1997年10月到中山大學工作，並聘為副教授，

1999年7月至2001年6月獲日本學術振興會（JSPS）資助在日本九州大學（Kyushu University）作博士后特別研究員。

曾講授《無機與分析化學》、《應用無機化學》、《無機化學實驗》、《配位化學》等本科生、研究生課程。指導碩士研究生、協助指導博士研究生。

功能金屬配合物超分子體系的分子設計、合成和結構與性能研究，重點在超分子配合物在催化、有機合成、分離、材料化學等領域中的應用。

1．鐵（III）－銅（II）異核細胞色素C氧化酶的模擬研究（日本學術振興會）

2．仿生水解酶的模研究（廣東省自然科學基金）

3．手性配合物的識別及組裝（教育部）

近年主要論著 (全部為SCI收錄)

1.Synthesis and Structural Characterization of Di- and Tetranuclear Zinc Complexes with Phenolate and Carboxylate Bridges. Correlations between 13C NMR Chemical Shifts and Carboxylate Binding Modes，Bao-Hui Ye*, Xiao-Yuan Li, Ian D. Williams, Xiao-Ming Chen, Inorg. Chem. 2002, 41(24), 6426-6431

2. Interlocking of molecular rhombi into a 2D polyrotaxane network via p-p interactions. Crystal structure of [Cu2(bpa)2(phen)2(H2O)2].2H2O (bpa2- = biphenyl-4,4'-dicarboxylate, phen = 1,10-phenanthroline). G.-F. Liu, B.-H, Ye, Y.-H. Liu, X.-M. Chen Chem. Commun. 2002, 1442-1443.

3. The design of new molecular "light switches" for DNA, X.-H. Zuo, B.-H. Ye, H. Li, Q.-L. Zhang, H. Chao, J.-G. Liu, L.-N. Ji, X.-Y. Li, J. Biol. Inorg. Chem. 2001, 6, 143.

4. Enantiomeric ruthenium(II) complexes binding to DNA: binding modes and enantioselectivity, J.-G. Liu, B.-H. Ye, Q.-L. Zhang, X.-H. Zou, Q.-X. Zhen, X. Tian and L.-N. Ji, J. Biol. Inorg. Chem., 2000, 5(1), 119-128.

5. A novel m3-cyano-bridged hetreotrimetallic 2-D coordination polymer constructed from rectangular grids, H. Zhang, J. Cai, X.-L. Feng, B.-H. Ye, X.-Y. Li, L.-N. Ji, J. Chem. Soc. Dalton Trans. 2000, 1687.

6. Three-dimensional coordination polymers self-assembled by unusual ligand-unsupported Ag-Ag bonds. Syntheses, structures and luminescent properties of [Ag2(H2L)3]nX2n (H2L = 1,4-bis(salicyladeneamino)butane, X- = NO3- and ClO4-), M.-L. Tong, X.-M. Chen, B.-H. Ye and L.-N. Ji, Angew. Chem. Int. Ed. Engl. 1999, 38(15), 2237-2240 .

7. GIAO nuclear magnetic shielding tensors in free base porphyrin and in magnesium and zinc metalloporphyrins, P. M. Kozlowski, K. Volinski, P. Pulay, B.-H. Ye and X.-Y. Li, J. Phy. Chem. A, 1999, 103(3), 420-425.

8. DFT-SQM force field for nickel porphine: intrinsic ruffling, P. M. Kozlowski, T. S. Rush III, A. A. Jarzecki, M. Z. Zgierski, B. Chase, C. Piffat, B.-H. Ye, X.-Y. Li, P. Pulay and T. G. Spiro, J. Phy. Chem. A, 1999, 103(10), 1357-1366.

9. Syntheses, characterization and third order non-linear optical properties of the ruthenium(II) complexes containing 2-phenyl-imidazo[4,5-f][1,10]phenanthroline derivatives, H, Chao, R-H. Li, B.-H. Ye, H. Li, X.-Long Feng, J.-W. Cai, J.-Y. Zhou and L.-N. Ji, J. Chem. Soc. Dalton Trans. 1999, 3711-3717.

10. Mono- and binuclear ruthenium(II) complexes containing a new asymmetric ligand 3-pyrazyl-as-triazino[5,6-f]1,10-phenanthroline: Synthesis, Characterization and DNA-binding properties, X.-H. Zou, B.-H. Ye, H Li, J.-G. Liu, Y. Xiong and L.-N. Ji, J. Chem. Soc. Dalton Trans. 1999, 1423-1428.

11. Clathration of Two-Dimensional Coordination Polymers: Synthesis and Structures of [M(4,4'-bpy)2(H2O)2](ClO4)2×(2,4'-bpy)2×H2O and [Cu(4,4'-bpy)2(H2O)2]](ClO4)4×(4,4'-H2bpy) (M=CdII, ZnII and bpy =bipyridine), M.-L. Tong, B.-H. Ye, J.-W. Cai, X.-M. Chen and S. W. Ng, Inorg. Chem. 1998, 37, 2645-2650.

12. Mononuclear Nickel Complexes Assembled into Two-dimensional Networks via Hydrogen Bonds and p-p Stacking interactions, B.-H. Ye, X.-M. Chen, G.-Q. Xue and L.-N. Ji, J. Chem. Soc. Dalton Trans. 1998, 2827-2827.

13. Helical Silver(I)-2,4'-bipyridine Chains Organized into 2-D Networks by Metal-counterion or Metal-metal Bonding. Structures of [Ag(2,4'-bipyridine)]X (X-= NO3- or ClO4-), M.-L. Tong, X.-M. Chen, B.-H. Ye and S. W. Ng, Inorg. Chem. 1998, 37, 5278.

14. The First Two Aqua-bridged Dimagnesium(II) complexes: Structural Models for Active Sites in Dimetallic Hydrolases, B.-H. Ye, T. Mak, I. D. Willams and X.-Y. Li, J. Chem. Soc. Dalton Trans. 1998, 1935-1936.

15. Electronic Paramagnetic Resonance and Magnetic Properties of Model Complexes for Binuclear Active Sites in Hydrolase Enzymes, B. E. Schultz, B.-H. Ye, X.-Y. Li. S. I. Chan, Inorg. Chem. 1997, 36(12), 2617-2622.

16. Novel Dimanganese(II) Complexes with (m-H2O)(m-OAc)2 Bridges. Model for Dimanganese Enzymes, B.-H. Ye, T. Mak, I. D. Williams and X.-Y. Li, Chem. Commun. 1997, 1813-1814.

17. Formation of a Novel Tetranuclear Iron(III) Complex with a m4-PO4 Bridge from 4-Nitrophenyl Phosphate, B.-H. Ye, X.-Y. Li, F. Xue and T. C. W. Mak, Chem. Commun. 1997, 2407-2408.

18. Bis(2,2'-bipyridine)ruthenium(II) Complexes with Imidazo[4,5-f][1,10]phenanthroline or 2-phenylimidazo[4,5-f][1,10]phenanthroline, J.-Z. Wu, B.-H. Ye, L. Wang, L-N. Ji, J.-Y. Zhou, R-H. Li, Z.-Y. Zhou, J. Chem. Soc. Dalton Trans. 1997, 1395-1401.

1．1996年“混配配合物的生物功能、作用機制及其應用探索”1996年獲廣東省自然科學一等獎。（第三完成人）

2．1998年“金屬酶體系的結構、機制和模擬研究”獲國家教育部科技進步二等獎（基礎類）。（第三完成人）

3．1998年“生物工程方法生產葡萄糖酸鋅（鎂、錳、內酯）新工藝的研究”獲國家教育部科技進步二等獎（發明類）。

4．1998年“含羧基與多胺基的金屬酶模型化合物的研究”獲廣東省自然科學一等獎。

5．200年“金屬酶模型化合物的結構、生物功能、作用機制之間規律性”獲中國高校自然科學二等獎。（第四完成人）

獲專利情況：

1994年“黑曲酶發酵生產葡萄糖酸鋅”獲中國專利局發明專利，1996年3月27日公開，公開號：CN119213A。