夏永姚
浙江師範大學客座教授
夏永姚
研究方向為物理化學和材料科學的交叉領域-功能材料電化學,當前主要的研究方向為(1)新型儲能材料和儲能技術的研究,包括液體鋰離子電池、電化學電容器、染料敏化太陽能電池、燃料電池等;(2)無機-有機納米複合材料在儲能、催化、光致發光、物質分離及生物醫藥等領域中的應用;3)功能材料的理論計算和模擬等研究。
2003年回國至今主持包括多項863計劃項目、國家自然科學基金重點基金、973計劃項目子課題、上海市優秀學科帶頭人計劃項目、國家自然科學基金面上項目,並與多家世界500強企業有合作研發項目。距今已發表SCI論文100餘篇,包括Nature Chemistry, J. Am. Chem. Soc,Angew. Chem. Int. Edit.,Adv. Mater.,Adv. Fun. Mater,Chem. Mater., J. Electrochem. Soc.等,被國際學術刊物他引近2000次,單篇被他引近400次;授權和申請專利25項;參與著書3本。目前多項研究成果已經產業化。
先後獲得的獎勵有:2002年度日本電化學會志優秀論文獎,2005年入選教育部新世紀優秀人才計劃,2009年國家自然科學基金委傑出青年基金獲得者,上海市優秀學科帶頭人。
1. Cui Wangjun, Li Feng, Liu Haijing, Wang Congxiao, Xia Yongyao. “Core-shell carbon-coated Cu6Sn5 prepared by in situ polymerization as a high-performance anode material for lithium-ion batteries“. Journal of Materials Chemistry. 19 (2009) 7202-7207. (Cover Page)
2. Liu Haijing, Cui Wangjun, Jin Linghua, Wang Congxiao, Xia Yongyao. “Preparation of three-dimensional ordered mesoporous carbon sphere arrays by a two-step templating route and their application for supercapacitors“. Journal of Materials Chemistry. 19 (2009) 3661-3667.
3. Liu Haijing, Jin Linghua, He Ping, Wang Congxiao, Xia Yongyao. “Direct synthesis of mesoporous carbon nanowires in nanotubes using MnO2 nanotubes as a template and their application in supercapacitors“. Chemical Communications. 44 (2009) 6813-6815.
4. Wang Xiaoming, Xia Yongyao. “FexC-C hybrid material as a support for Pt anode catalyst in direct formic acid fuel cell“. Electrochemistry Communications. 11 (2009) 28-30.
5. Yang Xinhui, He Ping, Xia Yongyao. “Preparation of mesocellular carbon foam and its application for lithium/oxygen battery“. Electrochemistry Communications. 11 (2009) 1127-1130.
6. Luo Jiayan, Chen Lijuan, Zhao Yujun, He Ping, Xia Yongyao. “The effect of oxygen vacancies on the structure and electrochemistry of LiTi2(PO4)3 for lithium-ion batteries: A combined experimental and theoretical study“. Journal of Power Sources. 194 (2009) 1075-1080.
7. Luo Jiayan, Xia Yongyao. “Electrochemical profile of an asymmetric supercapacitor using carbon-coated LiTi2(PO4)3 and active carbon electrodes“. Journal of Power Sources. 186 (2009) 224-227.
7. Wang Xiaoming, Xia Yongyao. “Synthesis, characterization and catalytic activity of an ultrafine Pd/C catalyst for formic acid electrooxidation“. Electrochimica Acta. 54 (2009) 7525-7530.
8. He Ping, Luo Jiayan, Yang Xinhui, Xia Yongyao. “Preparation and electrochemical profile of Li0.33MnO2 nanorods as cathode material for secondary lithium batteries“. Electrochimica Acta. 54 (2009) 7345-7349.(
9. He Ping, Luo Jiayan, He Jianxin, Xia Yongyao. “Electrochemical Profile of Oxygen-Deficient LiMn2O4-delta in Aqueous Electrolyte“. Journal of the Electrochemical Society. 156 (2009) A209-A214.
11. Wu Wen, Wang Yonggang, Li Feng, Xia Yongyao. “Electrochemical Capacitance Performance of Ordered Mesoporous Co3O4 Synthesized by Template Method“. Chinese Acta Chimica Sinica. 67 (2009) 208-212.
12. Huan-Ming Xiong*, Yang Xu, Qing-Guang Ren, and Yong-Yao Xia* , “Stable Aqueous ZnO@Polyner Core#Shell Nanoparticles with Tunable Photoluminescence and Their Application in Cell Imaging”, Journal of the American Chemical Society ,130(24),7522-7523(2008)
13. Huan-Ming Xiong*, Xiao-Yan Guan,Ling-Hua Jin, Wenn-Wen Shen,Hao-Jie Lu*,and Yong-Yao Xia* , “Surfactant-Free Synthesis of SnO 2 @PMMA and TiO 2 @PMMA Core-Shell Nanobeads Designed for Peptide/Protein Enrichment and MALDI-TOF MS Analysis”, Angew.Chem.Int.Ed, 47 4204-4207(2008)
14. Yong-Gang Wang, Wen Wu, Liang Cheng, Ping He, Cong-Xiao Wang* and Yong-Yao Xia* , “A Polyaniline Intercalated Layered Manganese Oxide Nanocomposite Prepared by Inorganic/Organic Interface Reaction and Its High Electrochemical Performance for Li Storage”, Advanced. Materials , 2166 (2008)
15. Wang-jun Cui, Cong-xiao Wang, and Yong-yao Xia *, “ Highly ordered three-dimensional macroporous FePO 4 as cathode materials for lithium-ion batteries”, Electrochemistry Communications , 10 ( 10) , 1587-1589 , ( 2008)
16. Xiao-Ming Wang, Yong yao Xia* ”electrocatalytic performance of PdCo-C catalyst for formic acid oxidation”, Electrochemistry Communications ,10, 16444-1646 (2008)
17. Hai-jing Liu, Shou-hang Bo, Wang-jun Cui, Feng Li, Cong-xiao Wang*, and Yong-yao Xia* , “Nano-sized cobalt oxide/mesoporous carbon sphere composites as negative electrode material for lithium-ion batteries”, Electrochim. Acta, 53(22) , 6497-6503(2008)
18. Guo-Xian Ma, Yong-Gang Wang, Cong-Xiao Wang*, Tian-Hong Lu*, Yong-Yao Xia*, “Hemoglobin immobilized on whisker-like carbon composites and its direct electrochemistry”, Electrochimica Acta 53,4738-4753(2008)
19. Jia-Yan Luo , Jin-Long Liu, Ping He, Yong-Yao Xia* ,“ A novel LiTi 2 (PO 4 ) 3 /MnO 2 hybrid supercapacitor in lithium sulfate aqueous electrolyte ”, Electrochimica Acta , 53, ( 28) , 8128-8133(2008)
20. Feng Li, Qing-Qing Zou, and Yong-Yao Xia *, “ CoO-loaded graphitable carbon hollow spheres as anode materials for lithium-ion battery” , Journal Power Sources , 177(2), 546-552 (2008)
21. Hui-Qiao Li,Yong-Gang Wang,Cong-Xiao Wang, Yong-Yao Xia *“A competitive candidate material for aqueous supercapactiors : High suface-area graphite” Journal Power Sources , 185 ( 2008 ) 1557-1562
22. Jing-jun Zhang, Ping He,Yong-yao Xia* “Electrochemical kinetics study of Li-ion in Cu6Sn5 electrode of lithium batteries by PITT and EIS”, Journal of Electroanalytical Chemistry 624 ,161-166 (2008)
23. Ping He, Xiao Zhang, Yong-Gang Wang, Liang Cheng, and Yong-Yao Xia * , “Lithium-ion Intercalation Behavior of LiFePO 4 in Aqueous and Nonaqueous Electrolyte Solutions”, Journal of Electrochem. Society , 155(2), A144-A150 (2008)
24. Jia-Yan Luo, Huan-Ming Xiong and Yong-Yao Xia *, “LiMn 2 O 4 Nanorods, Nano-thorn Microspheres, and Hollow Nanospheres as Enhanced Cathode Materials of Lithium-ion Battery ”, Journal Physical Chemistry C , 112 (31), 12051–12057( 2008)
25. Jia-Yan Luo , Dan-Dan Zhou, Jin-Long Liu, Yongyao Xia *,“ Hybrid aqueous energy storage cells using activated carbon and lithium-ion intercalated compounds - IV. Possibility of using polymer gel electrolyte Source”, Journal of the Electrochemical Society , 155 ( 11) A789-A793 ( 2008)
26. Xiao Zhang, Cong-Xiao Wang*, Fu-You Li*, and Yong-Yao Xia *, “ A quasi-solid-state dye-sensitized solar cell based on porous polymer electrolyte membrane”, Journal of Photochemistry and Photobiology A: Chemistry, 194(1), 31-36 (2008)
27. Xiao Zhang, Jing-Jun Zhang, Yong-Yao Xia*, “Molecular design of coumarin dyes with high efficiency in dye-sensitized solar cells” , Journal of Photochemistry and Photobiology A:Chemistry , 194, 167-172 (2008)
28. Jia-Yan Luo and Yong-Yao Xia *, “ Aqueous Lithium-ion Battery LiTi 2 (PO 4 ) 3 /LiMn 2 O 4 with High Power and Energy Densities as well as Superior Cycling Stability”, Advanced Functional Materials , 17 (18), 3877-3884 (2007).
29. Yong Gang Wang, Liang Cheng, HuanMin Xiong, and Yong-Yao Xia*, “High electrocatalytic activity of oxygen reduction on an air electrode based on Mn 3 O 4 /mesoporous carbon”, Chemistry of Materials, 19, 2095 – 2101 ( 2007).
30. Jia-yan Luo, Yong-gang Wang, Huan-ming Xiong* and Yong-Yao Xia*, “Ordered Mesoporous Spinel LiMn 2 O 4 by a Soft-Chemical Process as a Cathode Material for Lithium-ion Batteries”, Chemistry of Materials, 19, 4791-4795 (2007).
31. Huan-Ming Xiong, Dong-Ping Xie, Xiao-Yan Guan, Yu-Jing Tan and Yong-Yao Xia*, “Ultrastable Blue-Emitting ZnO@Polymer Core-Shell Nanoparticles and Microspheres”, Journal of Materials Chemistry, 17 (24): 2490-2496 (2007). (Cover page).
32. Jing-jun Zhang, Xiao Zhang and Yong-Yao Xia * , “ Co doped Co x Cu 6- x Sn 5 Alloys as Negative Electrode Materials for Rechargeable Lithium Batteries”,Journal of Electrochem. Soc , 154(1), A7-A13 (2007).
33. Yong-gang Wang, Jia-yan Lou, Wen Wu, Cong-xiao Wang* and Yong-Yao Xia * , “ Hybrid Aqueous Energy Storage Cells Using Activated Carbon and Lithium-ion Intercalated Compounds. III. Capacity fading mechanism of Li Co 1/3 Ni 1/3 Mn 1/3 O 2 at different pH electrolyte solutions”, Journal of Electrochem. Society , 154 (3), A228-A234 (2007).
34. Liang Cheng, Xi-Li Li, Hai-Jing Liu, Huan-Ming Xiong, Ping-Wei Zhang and Yong-Yao Xia * , “ Carbon Coated Li 4 Ti 5 O 12 as a High Rate Electrode Material for Electrochemical Supercapacitors” , Journal of Electrochem. Society , 154 (7), A228-A234 (2007).
35. Huiqiao Li, Jiayan Luo, Xufeng Zhou, Chengzhong Yu* and Yong-Yao Xia*, “A new ordered mesoporous carbon with short pore length and its electrochemical performances in supercapacitor application” , Journal of Electrochem. Society , 154 (8), A731-A736 (2007).
36. Jia-Yan Luo, and Yong-Yao Xia*, “ Effect of Pore Structure on the Electrochemical Capacitive Performance of MnO 2 ”,Journal of Electrochem. Society , 154 (11), A987-A992 (2007).
37. Jiayan Luo, Liang Cheng and Yong-Yao Xia* , “ Single-Crystal LiMn 2 O 4 Hollow Nanospheres Electrode Material with Exellent Cycling Reversibility and Rate Capability”, Electrochemistry Communications, 9, 1404-1409 (2007).
38. Xiao Zhang, Jing-Jun Zhang, and Yong-Yao Xia*, “A comparative theoretical investigation of ruthenium dyes in dye-sensitized solar cells”, Journal of Photochemistry and Photobiology A: Chemistry, 185, 283-288 (2007).
39. Jia-Yan Luo, Xi-Li Li and Yong-Yao Xia * , “ Low-Temperature, Soft-Chemistry Method to Synthesize Highly Crystalline LiMn 2 O 4 Spinel Cathode Materials”, Electrochimica Acta, 52, 4525-4531 (2007)
40. Hui-qiao Li, Ying Zou, and Yong-Yao Xia*, “A study of nitroxide polyradical/activated carbon composite as the positive electrode material for electrochemical hybrid capacitor”, Electrochimica Acta, 52(5), 2153-2157 (2007) .
41. Jing-jun Zhang, Yi-min Zhang, Xiao Zhang and Yong-Yao Xia* , “ Ni x Cu 6- x Sn 5 Alloys as Negative Electrode Materials for Rechargeable Lithium Batteries”, Journal Power Sources , 167, 171-177 (2007).
42. Guo-Xian Ma, Tian-Hong Lu* and Yong-Yao Xia * , “ Direct electrochemistry and bioelectrocatalysis o f hemoglobin immobilized on carbon black” , Journal of Bioelectrochemistry , 71, 180-185 (2007).
43.Xin-Hui Yang, Yong-Gang Wang, Huan-Ming Xiong* and Yong-Yao Xia ,* , “Interfacial Synthesis of Porous MnO 2 and Its Application in Electrochemical Capacitor”, Electrochimica Acta, 53, 752-757 (2007).
44. Hui-Qiao Li, Rui-Li Liu, Dong-Yuan Zhao* and Yong-Yao Xia*, “Electrochemical properties of an ordered mesoporous carbon prepared by direct tri-constituent co-assembly” , Carbons , 45, 2628–2635 (2007)