湯傑

1996年回國工作。

有機合成與有機合成方法學、金屬有機化學、甾體藥物化學。

湯傑他主持國家自然科學基金、上海市科委重點研究項目有多項。

主要論文及專利：

1. An efficient silica-grafted poly-(L)-leucine catalyst for asymmetric epoxidation of a, b-unsaturated ketone, J. Mol. Catal. A: Chemical, 2007

徠2. Palladium-Catalyzed Ring Enlargement of Aryl-Substituted Methylene- cyclopropanes to Cyclobutenes, J. Am. Chem. Soc., 2006, 128, 7430-7431.

3. Palladium-Catalyzed Cross-Coupling Reaction of 2-Iodo-4-(phenylchalcogenyl) -1-butenes, J. Org. Chem., 2005, 70, 10420-10425.

4. Enynylation of 2-Iodo-4- (phenylchalcogenyl) -1-butenes via Intramolecular Chelation: Approch to the Synthesis of Conjugated Dienynes or Trienynes, Org. Lett., 2005, 7(14), 3085.

5. Palladium-benzimidalium salt catalyst systems for Suzuki coupling: development of a practical and highly active palladium catalyst system for coupling of aromatic halides with arylboronic acids, Tetrahedron, 2005, 61, 9783-9790.

6. Asymmetric epoxidation of a,b-unsaturated ketones catalyzed by silica-grafted poly-(L)-leucine catalysts, Tetrahydron Lett., 2005, 46, 5665.

7. A Novel and Efficient Process for Preparation of 2,4-Diphenyl-4-methyl-1- pentene in Brönsted Acidic Ionic Liquid [Hmim]+BF4-, Chin. J. Chem., 2005, 23, 581.

8. Suzuki Coupling Reaction Catalyzed by Cyclopalladated Complexes of Tertiary Arylamines in Ionic Liquid, Chin. Chem. Lett., 2005, 16(9), 1173.

9. Oxidation of toluenes to benzoic acids by oxygen in non-acidic solvents, Tetrahedron, 2004, 60, 1225.

10. An unprecedented rhodium-catalysed self-conjugate reduction, cross-coupling tandem reaction of cinnamaldehydes with arylboronic acids, Chem. Commun., 2004, 1192-1193.

11. An efficient procedure for protection of carbonyls in Bronsted acidic ionic liquid [Hmim]BF4, Tetrahedron Lett., 2004, 45(25), 4963.

12. Immobilization of HX: [Hmim]X as Halogenating Agent, Recyclable Catalyst and Medium for Conversion of Alcohols to Alkyl Halides, Chin. J. Chem., 2004, 22, 619.

13. Homocoupling of Aryl Iodides Catalyzed by Cyclopalladated Complexes of Tertiary Arylamines, Chin. J. Chem., 2004, 22(5), 419.

14. Bronsted Acidic Ionic Liquid 1-Methylimidazolium Tetrafluoroborate: A Green Catalyst and Recyclable Medium for Esterification, Green Chemistry, 2003, 5, 38.

15. Rhodium-catalyzed Heck-type reaction of arylboronic acids with a,b-unsaturated esters: tuning b-hydrogen elimination vs. hydrolysis of alkylrhodium species, Chem. Commun., 2003, 2438.

16. Cross-coupling of arylboronic acids with terminal alkynes in air, Tetrahedron Lett., 2003, 44, 8709–8711.

17. Developing an ionic medium for ligandless-palladium-catalysed Suzuki and Heck couplings, J. Mol. Catalysis A: Chemical, 2003, 206, 193-198.

18. Synthesis, Biochemical Properties and Molecular Modelling Studies of Organometallic Specific Estrogen Receptor Modulators (SERMs), the Ferrocifens and Hydroxyferrocifens: Evidence for an Antiproliferative Effect of Hydroxyferrocifens on both Hormone-Dependent and Hormone-Independent Breast Cancer Cell Lines, Chem. Eur. J. 2003, 9, 5223-5236.

19. Heptadecafluorooctanesulfonic acid catalyzed reactions of methylenecyclopropanes on aromatic amines, sulfonamides and alcohols in supercritical carbon dioxide, Green Chem., 2003, 5, 85-88.

20. Crystal Structure of Chiral Acetato-bridged Binuclear Cyclopalladated Complex [Pd(μ-O2CMe)(S-C6H4CHMeNH2)]2, Chin. J. Chem., 2003, 21(8), 1039.

21. Heck reaction of iodoarenes with methyl acrylate catalyzed by cyclopalladated complexes of tertary arylamines immobilized in ionic liquid [Bmim]+BF4-, Chin. J. Chem., 2003, 21, 1111.

22. Synthesis of cyanobenzaldehydes (o-, m-, p-) by molecular oxygen oxidation methods, Chin. J. Chem., 2002, 20, 76.

23. Cyclopalladated complexes of tertiary arylamines catalyzing the Heck reaction in ionic liquid [Bmim]+BF4, J. Organomet. Chem., 2002, 651, 146.

24. Immobilization of Pd(II) catalysts for cyclopropanation of ionic liquid, Chin. J. Chem., 2002, 20, 114.

25. A novel ring-opening reaction of methylenecyclopropanes with aromatic amines catalyzed by Lewis acids, Tetrahedron Letters, 2002, 43, 8019-8024.

26. A New Convenient Method for the Synthesis of Formyl Ferrocene, Syn. Commun., 2000, 1657.

1999年獲“上海市育才”獎和華東師範大學“奧力孚”獎；2002年獲“寶鋼優秀教師”獎，同年被評為“教育部優秀骨幹教師”；2004年獲“上海市優秀教育工作者”、華東師範大學“師德標兵”稱號；2005年獲華東師範大學“優秀德育工作者”稱號。