張正彪

2000年在蘇州大學工作。

2007年8月至2008年8月赴新加坡國立大學E. T Kang教授和K. G. Neoh教授課題組作博士后一年。

2012年2月至2013年2月赴美國Akron大學Stephen Cheng教授課題組作訪問學者一年。

2014年江蘇省高校“青藍工程”優秀青年骨幹教師培養對象。

2015年6月至8月赴日本名古屋大學Kamigaito教授課題組作訪問教授。

主要開設《高分子化學（雙語）》等主幹課程。

研究領域為高分子合成，迄今已發表SCI收錄論文150多篇，已獲授權中國發明專利20多項，獲得國家自然科學基金多項。

科研項目

國家自然科學基金面上項目“基於可逆Diels-Alder反應構建複雜拓撲鏈結構以及分子量/序列明確的聚合物”（21674072）；2017.1-2020.12，項目負責人。

國家自然科學基金面上項目“基於非共價鍵相互作用和可控自由基聚合的大分子精密合成”（21174094）；2012.1-2015.12，項目負責人；

國家自然科學基金面上項目“室溫下零價鐵調控的“活性”/可控自由基聚合”（21174094）；2012.1-2015.12，項目負責人；

國家自然科學基金青年基金項目“單電子轉移活性自由基聚合（SET-LRP）的機理研究”（20904036），2010.1-2012.12，項目負責人；

江蘇省高校自然科學研究計劃重大基礎研究項目"基於活性自由基聚合和分子間弱相互作用的大分子精密合成" (2012.8-2015.12)，項目負責人；

江蘇省高校自然科學基金項目“ATRP表面接枝法製備抗菌和抗紫外功能性真絲織物的研究”（09KJB150010），2009.9-2011.12，項目負責人；

江蘇省高校省級重點實驗室開放課題“絲素膜表面的AGET-ATRP改性以及其作為細胞生長載體的研究”（KJS0913），2009.9-2010.12，項目負責人；

研究領域

大分子結構設計及其精密合成；序列明確/可控聚合物的設計與合成；拓撲聚合物的合成；功能高分子的設計和合成。

代表論文

1.Yuxuan Ji, Liuqiao Zhang, Xue Gu, Wei Zhang, NianchenZhou, Zhengbiao Zhang,* andXiulin Zhu. Sequence-Controlled Polymers with Furan-Protected Maleimide as aLatent Monomer. Angew. Chem. Int. Ed. 2017, 56, 2328-2333.

2.Wei Chen, YanyanZhou, Ying Li, Jun Sun, Xiangqiang Pan, Qian Yu, Nianchen Zhou, Zhengbiao Zhang* and Xiulin Zhu. Shape-memory and self-healingpolyurethanes based on cyclic poly(ε-caprolactone). Polym. Chem., 2016, 7, 6789-6797.

3.Junfei Zhao, Yanyan Zhou, Yu Zhou, Nianchen Zhou,Xiangqiang Pan, Zhengbiao Zhang*and Xiulin Zhu. A straightforward approach for the one-pot synthesis of cyclicpolymers from RAFT polymers via thiol–Michael addition. Polym. Chem., 2016, 7,1782-1791.

4.Chunlai Ding, Caiwei Fan, Ganquan Jiang, XiangqiangPan, Zhengbiao Zhang*, JianZhu* and Xiulin Zhu. Photocatalyst-Free and Blue Light-Induced RAFT Polymerizationof Vinyl Acetate at Ambient Temperature. MacromolecularRapid Communications. 2015,36, 2181-2185.

5.Zhiwei Lin, Pengtao Lu, Xinfei Yu, Wen-Bin Zhang,Mingjun Huang, Kan Wu, Kai Guo, Chrys Wesdemiotis, Xiulin Zhu, Zhengbiao Zhang*, Kan Yue* andStephen Z. D. Cheng*. Sequential “Click” Synthesis of “Nano-Diamond-Ring-like”Giant Surfactants Based on Functionalized Hydrophilic POSS/C60 Tethered withCyclic Polystyrenes. Macromolecules 2014, 47, 4160-4168.

6.ZhihaoHuang, Yanyan Zhou, Zimu Wang,Ying Li, Wei Zhang, Nianchen Zhou, ZhengbiaoZhang and Xiulin Zhu. Recent Advances of CuAAC Click Reaction In Building Cyclic Polymer.Chinese Journal of Polymer Science 2017, 35,317-341. Reviewarticle.

7.Zhaoxiong Cai, Weihong Lu, Feng Gao,Xiangqiang Pan, * Jian Zhu, ZhengbiaoZhang* Xiulin Zhu*. Diselenide-Labeled Cyclic Polystyrene with MultipleResponses: Facile Synthesis, Tunable Size, and Topology. Macromol. Rapid Commun. 2016,37, 865-871.

8.Shuangshuang Zhang, Lu Yin, Wei Zhang*, Zhengbiao Zhang* and XiulinZhu*. Synthesis of Diverse Cyclic-Brush Polymers with Cyclic Polystyrene asUniversal Template via Grafting-from Approach. Polym. Chem., 2016, 7,2112-2120.

9.Qingqing Liu, Huaqiao Wu, Liuqiao Zhang, Yu Zhou,Wei Zhang, Xiangqiang Pan, ZhengbiaoZhang* and Xiulin Zhu. RAFT polymerization of N-vinylpyrrolidonemediated by cyanoprop-2-yl-1-dithionaphthalate in the presence of afluoroalcohol: the possibility of altering monomer properties by hydrogenbonding? Polym. Chem., 2016, 7, 2015-2021.

10.Yunshu Wang, Shuangshuang Zhang, Laibing Wang, WeiZhang*, Nianchen Zhou, ZhengbiaoZhang* and Xiulin Zhu*. The Suzuki coupling reaction as apost-polymerization modification: a promising protocol for construction ofcyclic-brush and more complex polymers. Polym. Chem., 2015, 6, 4669-4677.

11.Feng Gao, Xiangqiang Pan,* Jian Zhu, Zhengbiao Zhang*, Wei Zhang andXiulin Zhu. Facile synthesis of well-defined redox responsivediselenide-labeled polymers via organoseleniummediated CRP and aminolysis. Polym. Chem., 2015, 6, 1367-1372.

12.Caiwei Fan, Chunlai Ding, Xiangqiang Pan, Zhengbiao Zhang*, Jian Zhu*, andXiulin Zhu. A Straightforward Method For Preparing Well-Defined ResponsiveDiselenide-containing Polymers Based on ATRP. Macromolecular Rapid Communications. 2015, 36, 903-908.

13.JunfeiZhao, Yanyan Zhou, Yiwen Li, Xiangqiang Pan, Wei Zhang, Nianchen Zhou, KeZhang, Zhengbiao Zhang* andXiulin Zhu*, Modular Construction ofMacrocycle-based Topological Polymers viaHigh-Efficient Thiol Chemistry, Polym.Chem., 2015, 6, 2879–2891.

14.Huaqiao Wu, Yingbo Wan, Wenxiang Wang, Yong Wang, NianchenZhou, Wei Zhang, Xiaohong Li,* ZhengbiaoZhang,* Xiulin Zhu, HydrogenBonding Promoting Controlled Radical Polymerization of 2-Vinyl Pyridine:Supramonomer for A Better Control, PolymerChemistry, 2015, 6, 2620-2625.

15.Feng Gao, Xiangqiang Pan, Jian Zhu, ZhengbiaoZhang, Wei Zhang, Xiulin Zhu Diselenocarbamates, Novel Initiators in ATRP ofStyrene, J. Polym. Sci., Part A: Polym.Chem. 2015, 53, 1927-1933.

16.Yuwei Gu, Junfei Zhao, Qingqing Liu, XiangqiangPan, Wei Zhang, Zhengbiao Zhang*,Xiulin Zhu*, Zero valent metal/RAFT agent mediated CRP of functional monomersat room temperature: a promising catalyst system for CRP. Polym. Chem., 2015, 6, 359-363.

17.Yiwen Li, Hao Su, Xueyan Feng, Kan Yue, Zhao Wang,Zhiwei Lin, Xiulin Zhu, Qiang Fu, ZhengbiaoZhang*, Stephen Z. D. Cheng*, Wen-Bin Zhang*. Precision synthesis ofmacrocyclic giant surfactants tethered with two different polyhedral oligomericsilsesquioxanes at distinct ring locations via four consecutive"click" reactions. Polym.Chem., 2015, 6, 827-837.

18.Yang Wu, Yanyan Zhou, Jian Zhu, Wei Zhang,Xiangqiang Pan, Zhengbiao Zhang*,Xiulin Zhu*. Fast conversion of terminal thiocarbonylthio group of RAFT polymerto "clickable" thiol group via the versatile sodium azide. Polym. Chem., 2014, 5, 5546-5550.

19.Wenxiang Wang, Junfei Zhao, Nianchen Zhou, JianZhu, Wei Zhang, Xiangqiang Pan, ZhengbiaoZhang* and Xiulin Zhu* Reversible Deactivation Radical Polymerizationin the Presence of Zero-Valent Metals: from Components to PrecisePolymerization. Polym. Chem. 2014, 5, 3533-3546. Review Article.

20.Yang Wu, Junfei Zhao, Xiaofei Zhang, Jian Zhu, WeiZhang,Zhengbiao Zhang* andXiulin Zhu* Zero-valent metal catalyzed removal of thiocarbonylthio end groupsfrom RAFT-made polystyrene: producing controllable bimodal molecular weightdistribution. Polym. Chem. 2014, 5, 1992-1998.

21.Zhigui Zheng, Wenxiang Wang, Yuan Zhou, Zhengbiao Zhang* and Xiulin Zhu*.Manganese(III) acetylacetonate initiated RAFT olymerizations: an alternativeand versatile RAFT nitiator. Polym. Chem.2014, 5, 37-42.

22.Ye Cai, Jinjie Lu, Feng Zhou, Xiaoji Zhou, NianchenZhou*, Zhengbiao Zhang*,Xiulin Zhu* Cyclic Amphiphilic Random Copolymers Bearing Azobenzene SideChains: Facile Synthesis and Topological Effects on Self-Assembly andPhotoisomerization. Macromol. RapidCommun. 2014, 35, 901−907.

23.YuweiGu, Junfei Zhao, Qingqing Liu, Nianchen Zhou, Zhengbiao Zhang*,Xiulin Zhu*. Zero-valent iron (Fe(0)) mediated RAFT miniemulsionpolymerization: a facile approach for the fabrication of Fe(0)-encapsulatedpolymeric nanoparticles Polym. Chem.,2014, 5, 4215−4218.

24.Wenxiang Wang, Junfei Zhao, Huali Yu, NianchenZhou, Zhengbiao Zhang*,Xiulin Zhu*. Simultaneously improving controls over molecular weight and stereoregularity ofPoly(4-vinylpyridine) via a hydrogen bonding-facilitated controlled radicalpolymerization. Polymer 2013, 54, 3248-3253.

25.Xiaofei Zhang, Yang Wu, Jun Huang, Xuelang Miao, Zhengbiao Zhang*, Xiulin Zhu*.Copper(0)-Mediated Radical Polymerization Of Styrene At Room Temperature. Chinese. J.Polym. Sci. 2013, 31, 702-712.

26.Xiaoji Zhou, Wenxiang Wang, Huali Yu, Junfei Zhao, Zhengbiao Zhang* and XiulinZhu*. Hydrogen bonding assisted reversible-deactivation radicalcopolymerization of 4-vinylpyridine and styrene: a facile approach foradjusting polymerization behavior, polymer composition.Polym. Chem. 2013, 4, 3575-3581.

27.Xiaofei Zhang, Wenxiang Wang, Kai Guo, ChrysWesdemiotis, Zhengbiao Zhang*,Xiulin Zhu*. Zero-valent metal catalyzed radical-induced adjustableremoval/modification of thiocarbonylthio end groups of RAFT polymer at ambienttemperature. Polym. Chem. 2013, 4, 637-644.

28.Yiyu Zhan, ZhengbiaoZhang*, Xiangqiang Pan, Jian Zhu, Nianchen Zhou, Xiulin Zhu*. A CyclicSelenium-Based Reversible Addition-Fragmentation Chain Transfer Agent MediatedPolymerization of Vinyl Acetate. J.Polym. Sci., Part A: Polym. Chem. 2013, 51, 1656-1663.

29.Wenxiang Wang, Junfei Zhao, Wei Zhang, Jian Zhu, Zhengbiao Zhang*, Xiulin Zhu*.Ligand-Free SET-DTLRP of MMA at Room Temperature. J.Polym. Sci., Part A: Polym. Chem. 2013, 51, 1872-1879.

30.Xing Zhu, Nianchen Zhou*, Jian Zhu, Zhengbiao Zhang*, Wei Zhang,Zhenping Cheng, Yingfeng Tu, Xiulin Zhu*. High-Effi ciency Preparation ofMacrocyclic Polymers via a Circulatory Extraction-Cyclization Strategy. Macromol. Chem. Phys. 2013, 214, 1107-1113.

31.Xing Zhu, Nianchen Zhou*, Jian Zhu, Zhengbiao Zhang*, Wei Zhang,Zhenping Cheng, Yingfeng Tu, Xiulin Zhu*. A High-Efficiency Strategy for Synthesizing Cyclic Polymers of Methacryatesin One Pot. Macromol. Rapid Commun. 2013, 34, 1014-1019.

32.Wenxiang Wang, ZhengbiaoZhang*, Zhenping Cheng, Jian Zhu, Nianchen Zhou, Xiulin Zhu*. Favorablehydrogen bonding in room-temperature Cu(0)-mediated controlled radicalpolymerization of 4-vinylpyridine. Polym.Chem. 2012, 3, 2731-2734.

33.Junfei Zhao, Wenxiang Wang,Liangjiu Bai, Lili Zhou, Zhenping Cheng, Zhengbiao Zhang*, Xiulin Zhu*. Reversible-deactivation radical polymerizationmediated byCuSO∙5HO: an alternative and promising copper(II)-basedcatalyst.Polym. Chem. 2012, 3, 3220-3223.

34.Lili Zhou, ZhengbiaoZhang*, Wenxiang Wang, Zhenping Cheng, Nianchen Zhou, Jian Zhu, WeiZhang, Xiulin Zhu*. Zero-Valent Bimetallic Iron/Copper Catalyzed SET-LRP: ADual Activation by Zero-Valent Iron. J.Polym. Sci.,Part A: Polym. Chem. 2012, 50, 936-943.

35.Wenxiang Wang, ZhengbiaoZhang*, Yang Wu, Jian Zhu, Zhenping Cheng, Nianchen Zhou, Wei Zhang,Xiulin Zhu*.Ligand-Free Cu(0)-Mediated Controlled Radical Polymerization ofMethyl Methacrylate at Ambient Temperature. J.Polym. Sci., Part A: Polym. Chem. 2012, 50, 711-719.

36.Huali Yu, ZhengbiaoZhang*, Zhenping Cheng, Jian Zhu, Nianchen Zhou, Wei Zhang, XiulinZhu*. ATRP of Styrene Catalyzed by Elemental Fe(0) and Br2: An Easy andEconomical ATRP Process. J.Polym. Sci., Part A: Polym. Chem. 2012, 50, 2182-2187.

37.Huali Yu, Yang Wu, Jinlong Gao, Wenxiang Wang, Zhengbiao Zhang* , Xiulin Zhu*.Copper(0)-Mediated Radical Copolymerization of Vinyl Acetate and Acrylonitrilein DMSO at Ambient Temperature.J.Polym. Sci., Part A:Polym. Chem. 2012, 50, 4983-4989.

38.Huali Yu, Qifeng Chen, Zhengbiao Zhang*, Jian Zhu, Zhenping Cheng, Nianchen Zhou,Wei Zhang, Xiulin Zhu*.60Co γ-irradiation-initiated RAFT polymerization of VAcat room temperature. React.Funct. Polym. 2012, 72, 153-159.

39.Lili Zhou,ZhengbiaoZhang*,Zhenping Cheng,Nianchen Zhou,Jian Zhu,Wei Zhang,XiulinZhu*.Fe(0) Powder/CuBr2-Mediated “Living”/Controlled Radical Polymerization ofMethyl Methacrylate and Styrene at Ambient Temperature.Macromol.Chem.Phys.2012,213,439-446.

40.Qin Zhang,ZhengbiaoZhang* Wenxiang Wang,Jian Zhu, Zhenping Cheng,Nianchen Zhou, WeiZhang, Xiulin Zhu*. SET-RAFT of MMA Mediated by Ascorbic Acid-Activated CopperOxide. J. Polym. Sci., Part A:Polym. Chem. 2012, 50, 1424-1433.