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陳霄

大連理工大學化工學院副教授

陳霄是美國南卡羅來納大學化學工程系的訪問學者。長期在大連理工任教。大連理工大學副教授,碩士生導師。

個人簡介


陳霄,男,大連理工大學,化工學院,化學工程與技術,副教授。

教育經歷


2004/09-2008/06,湖南大學,化工學院,學士
2008/09-2013/10,大連理工大學,化工學院,博士

研究經歷


2011/07-2011/10,美國南卡羅來納大學,化學工程系,訪問學者
2013/10-2015/12, 大連理工大學,化工學院,化學工程與技術,講師
2015/7-至今,大連理工大學,化工學院,化學工程與技術,碩士生導師
2015/12-至今,大連理工大學,化工學院,化學工程與技術,副教授

研究領域


多相催化;催化新材料;金屬間化合物
目前承擔科研課題名稱、來源
1.過渡金屬硅化物催化新材料的微波輔助製備、表徵及其加氫脫氧性能,國家自然科學青年基金項目(21403026),2015/01-2017/12、項目負責人。
2.鋁基金屬間化合物化學氣相沉積法製備及選擇加氫性能,中國博士后科學基金特別資助項目(2015T80255),2015/03-2016/06、項目負責人。
3.金屬硅化物催化新材料的膠體化學法選控制備及加氫性能,中國博士后科學基金項目(2014M551068),2013/12-2015/12、項目負責人。
4.鋁基金屬間化合物催化新材料化學氣相沉積法製備及選擇加氫性能,遼寧省自然科學基金-瀋陽材料科學國家(聯合)實驗室聯合開放基金項目(2015021014),2016/01-2017/12、項目負責人。
5.金屬鋁化物催化新材料的金屬有機化學氣相沉積可控制備及其選擇加氫性能研究,大連理工大學基本科研業務費科研專題項目(DUT14RC(3)007),2013/12-2015/12、項目負責人。
6.苯酐選擇性催化還原制苯酞技術的研究和開發,企業委託研發項目,2014/06-2016/04、項目共同負責人。7.煙氣協同脫硝脫汞催化劑的研製,企業委託研發項目,2015/03-2016/03、項目共同負責人。
8.煤焦油加氫測試服務協議,企業委託研發項目,2015/01-2015/12、項目共同負責人。
9.體相和負載雙金屬硅化物催化新材料的理性設計、化學製備及其加氫脫硫性能,國家自然科學基金面上項目(21373038),2014/01-2016/12、項目主要參與人。
10.中低溫煤焦油催化提質生產清潔燃料技術的研究開發,企業委託研發項目,2012/01-2014/12、項目主要參與人。

研究方向


1. 金屬間化合物催化新材料的選控合成及加氫性能的研究
2. 非常規能源清潔能源化
3. 催化加氫制精細化學品
4. 環境催化

著作論文


期刊論文:
1. Xiao Chen, Anqi Zhao, Zhengfeng Shao, Chuang Li, Christopher T. Williams, Changhai Liang*, “Synthesis and Catalytic Properties for Phenylacetylene Hydrogenation of Silicide Modi?ed Nickel Catalysts”, J. Phys. Chem. C, 2010, 114, 16525-16533.
2. Xiao Chen, Anqi Zhao, Zhengfeng Shao, Zhiqiang Ma, Changhai Liang*, “A Novel Approach to Synthesize Highly Selective Nickel Silicide Catalysts for Phenylacetylene Semihydrogenation”, Stud. Surf. Sci. Catal., 2010, 175, 77-84.
3. Xiao Chen, Xinkui Wang, Jinghai Xiu, Christopher T. Williams, Changhai Liang*, “Synthesis and Characterization of Ferromagnetic Nickel-Cobalt Silicide Catalysts with Good Sulfur Tolerance in Hydrodesulfurization of Dibenzothiophene”, J. Phys. Chem. C, 2012, 116, 24968-24976.
4. Xiao Chen, Miao Li, Jingchao Guan, Xinkui Wang, Christopher T. Williams, Changhai Liang*, “Nickel-Silicon Intermetallics with Enhanced Selectivity in Hydrogenation Reactions of Cinnamaldehyde and Phenylacetylene”, Ind. Eng. Chem. Res., 2012, 51, 3604–3611.
5. Xiao Chen, Bingsen Zhang, Chuang Li, Zhengfeng Shao, Dangsheng Su, Christopher T. Williams, Changhai Liang*, “Structural and Electrochemical Properties of Nanostructured Nickel Silicides by Reduction and Silici?cation of High-surface-area Nickel Oxide”, Mater. Res. Bull., 2012, 47, 867-877.
6. Xiao Chen, Xin Liu, Lei Wang, Miao Li, Christopher T. Williams, Changhai Liang*, “High Sulfur Tolerance of Ni-Si Intermetallics as Hydrodesulfurization Catalysts”, RSC Adv., 2013, 3, 1728-1731.
7. Xiao Chen, Jingchao Guan, Guangyan Sha, Zhanming Gao, Christopher T. Williams, Changhai Liang*, “Preparation and magnetic properties of single phase Ni2Si by reverse Rochow reaction”, RSC Adv., 2014, 4, 653-659.
8. Xiao Chen, Jianhui Jin, Guangyan Sha, Chuang Li, Bingsen Zhang, Dang Sheng Su, Christopher T Williams, Changhai Liang*, “Silicon-nickel Intermetallic Compounds Supported on Silica as a Highly Efficient Catalyst for CO Methanation”, Catal. Sci. Technol., 2014, 4, 53-61. (Inside Cover)
9. Xiao Chen, Mingming Zhang, Kaixuan Yang, Christopher T. Williams, Changhai Liang*, “Raney Ni-Si Catalyst for Selective Hydrogenation of Highly Concentrated 2-Butyne-1,4-Diol to 2-Butene-1,4-Diol in Aqueous Phase”, Catal. Lett., 2014, 144, 1118–1126.
10. Xiao Chen, Yue Ma, Lei Wang, Zonghan Yang, Shaohua Jin, Liangliang Zhang, Changhai Liang*, “Ni-Al Intermetallic Compounds as Excellent Selective and Stable Catalysts for Hydrogenation of Naphthalene to Tetralin”, ChemCatChem, 2015, 7, 978-983.
11. Xiao Chen, Junhu Wang, Changhai Liang*, "Synthesis and M?ssbauer spectroscopic investigation of Fe-based silicides", M?ssbauer Effect Reference and Data Journal, 2015, 38, 157-178.
12. Anqi Zhao, Xiao Chen, Jingchao Guan, Christopher T. Williams, Changhai Liang*, “The Formation Mechanism of Cobalt Silicide on Silica from Co(SiCl3)(CO)4 by in situ Fourier Transform Infrared Spectroscopy”, Phys. Chem. Chem. Phys., 2011, 13, 9432-9438.
13. Miao Li, Xiao Chen, Jingchao Guan, Xinkui Wang, Junhu Wang, Christopher T. Williams, ChanghaiLiang*, “A Facile and Novel Approach to Magnetic Fe@SiO2 and FeSi2@SiO2 Nanoparticles”, J. Mater. Chem., 2012, 22, 609-616.
14. Miao Li, Xiao Chen, Jingchao Guan, Junhu Wang, Changhai Liang*, “Thermally induced phase transition and magnetic properties of Fe–FeSi2 with core–shell structure”, Phys. Status Solidi A, 2013, 210, 2710-2715.
15. Jingchao Guan, Xiao Chen, Kaixuan Yang, Alexandre Rykov, Junhu Wang and Changhai Liang*, “Preparation and size-dependent magnetism of highly dispersed iron silicide nanoparticles on silica”, J. Mater. Chem. C, 2014, 2, 5292-5298. (Back Cover)
16. Liangliang Zhang, Xiao Chen, Shaohua Jin, Jingchao Guan, C. T. Williams, Zhijian Peng, Changhai Liang*, “Rapid microwaves synthesis of CoSix/CNTs as novel catalytic materials for hydrogenation of phthalic anhydride”, J. Solid State Chem., 2014, 217, 105-112.
17. Jin Guo, Xiao Chen, Yanjiao Yi, Wenzhen Li and Changhai Liang*, “Layer-controlled synthesis of graphene-like MoS2 from single source organometallic precursor for Li-ion batteries”, RSC Adv., 2014, 4, 16716-16720.
18. Kaixuan Yang, Xiao Chen, Jingchao Guan, Changhai Liang*, “Nickel Silicide Prepared from Organometallic Polymer as Efficient Catalyst towards Phenylacetylene Hydrogenation”, Catal. Today, 2014, revised.
19. Jin Guo, Xiao Chen, Shaohua Jin, Mingming Zhang and Changhai Liang*, “Synthesis of graphene-like MoS2 nanowall/graphene nanosheet hybrid materials with high lithium storage performance”, Catal. Today, 2014, revised.
20. Anqi Zhao, Xiaofei Zhang, Xiao Chen, Jingchao Guan, and Changhai Liang*, “Cobalt Silicide Nanoparticles in Mesoporous Silica as Efficient Naphthalene Hydrogenation Catalysts by Chemical Vapor Deposition of Co(SiCl3)(CO)4 Precursor”, J. Phys. Chem. C, 2010, 114, 3962-3967.
21. Zhengfeng Shao, Chuang Li, Xiao Chen, Xinkui Wang, Changhai Liang*, “A Facile and Controlled Route to Prepare Eggshell Pd Catalyst for Selective Hydrogenation of Phenylacetylene”, ChemCatChem, 2010, 2, 1555-1558.
22. Jingchao Guan, Anqi Zhao, Xiao Chen, Mingming Zhang, Changhai Liang*, “Chemical Vapor Deposition of Fe(CO)4(SiCl3)2 for the Synthesis of Hydrogenation Catalyst Made of Highly Dispersed Iron Silicide Particles on Silica”, Stud. Surf. Sci. Catal., 2010, 175, 259-262.
23. Jingchao Guan, Jianhui Jin, Xiao Chen, Bingsen Zhang, Dangsheng Su, and Changhai Liang*, “Preparation and Formation Mechanism of Highly Dispersed Manganese Silicide on Silica by MOCVD of Mn(CO)5SiCl3”, Chem. Vap. Deposition, 2013, 19, 68-73.
24. Qian Liu, Chuang Li, Xiao Chen, Changhai Liang*, “Shape and Size Controlled Sythesis of Pd Nanoparticles for Selective Hydrogenation of 1,4-Butynediol”, J. Mole. Catal. (China), 2013, 27, 316-322.
25. Anqi Zhao, Xiaofei Zhang, Jingchao Guan, Xiao Chen, Changhai Liang*, “Preparation of Cobalt Silicides and Their Catalytic Property of Naphthalene Hydrogenation”, Sciencepaper Online, 2009, 4(12), 855-858.
26. Shaohua Jin, Zihui Xiao, Chuang Li, Xiao Chen, Lei Wang, Jiacheng Xing, Wenzhen Li, Changhai Liang*, “Catalytic Hydrodeoxygenation of Anisole as Lignin Model Compound over Supported Nickel catalysts”, Catal. Today, 2014, 234, 125-132.
27. Lei Wang, Huihui Wan, Shaohua Jin, Xiao Chen, Chuang Li, Changhai Liang*, “Hydrodeoxygenation of dibenzofuran over SiO2, Al2O3/SiO2 and ZrO2/SiO2 supported Pt catalysts”, Catal. Sci. Technol., 2014, DOI: 10.1039/C4CY00859F.
28. Xinkui Wang*, Qinggang Liu, Zihui Xiao, Xiao Chen, chuan shi, Shengyang Tao, Yanqiang Huang, Changhai Liang, “In-situ synthesis of Au-Pd bimetallic nanoparticles on amine-functionalized SiO2 for the aqueous-phase hydrodechlorination of chlorobenzene”, RSC Adv., 2014, DOI: 10.1039/C4RA07122K.
29. Xiao Chen, Junhu Wang, Kaixuan Yang, Changgong Meng, Christopher T. Williams, Changhai Liang*,“Structure Investigation and Dibenzothiophene Hydrodesulfurization Properties of Fe-Substituted Ni-Si Intermetallics”,J. Phys. Chem. C 2015, 119, 29052?29061 ,DOI: 10.1021/acs.jpcc.5b10773.
會議論文:
1. Xiao Chen, Xin Liu, Lei Wang, Changhai Liang, The international symposium on "Molecular Aspects of Catalysis by Sulfides" (MACS VI), France, 2013, Oral Presentation
2. Xiao Chen, Christopher T. Williams, Bingsen Zhang, Dangsheng Su, Changhai Liang, SynFuel2012 symposium, Germany, 2012, Poster
3. Xiao Chen, Changhai Liang, “Nickel silicides: an alternative and high sulfur resistant catalyst for hydrodesulfurisation”, the ICC 2012 Congress -15th International Congress on Catalysis, Germany, 2012, Poster Presentation
4. Xiao Chen, Chuang Li, Christopher T. Williams, and Changhai Liang, “Magnetic, Electrochemical and Catalytic Properties of Nickel Silicides Prepared by Direct Silicification Method”, Southeastern Catalysis Society 10th Annual Fall Symposium , United States, 2011, Poster
5. Xiao Chen, Christopher T. Williams, and Changhai Liang, “Synthesis and Catalytic Properties of Nickel Silicide Catalysts for Selective Hydrogenation”, AlChE 2011 Annual Meeting, United States, 2011, Poster
6. Xiao Chen, Miao Li, Jingchao Guan, Changhai Liang, The 7th National Congress on Environmental catalytic and materials, China, 2011, Oral Presentation
7. Xiao Chen, Miao Li, Jingchao Guan, Changhai Liang, The 13th National Youth Conference on Catalysis, China, 2011, Excellent Poster
8. Xiao Chen, Anqi Zhao, Zhengfeng Shao, Zhiqiang Ma, Changhai Liang, “A Novel Approach to Synthesize Highly Selective Nickel Silicide Catalysts for Phenylacetylene Semihydrogenation” The 10th international symposium on the "Scientific Bases for the Preparation of Heterogeneous Catalysts", 2010, Oral Presentation
9. Xiao Chen, Anqi Zhao, Jingchao Guan, Miao Li, Jianhui Jin, Changhai Liang, The 15th National Congress on Catalysis, China, 2010, poster
10. Miao Li, Xiao Chen, Jingchao Guan, Junhu Wang, Changhai Liang, 8th International Symposium on M?ssbauer Spectroscopy, China, 2012, Poster Award
專利:
1. 梁長海,陳霄,李苗,管婧超,一種過渡金屬硅化物加氫脫硫催化劑及其製備方法,2012.11,中國,ZL201110134107.1
2. 梁長海,趙安琪,管婧超,陳霄,一種高性能負載型金屬硅化物催化劑、製備方法及其應用,2012.01,中國,ZL200910307122.4
3. 梁長海,邵正鋒,李闖,陳霄,反應沉積法製備蛋殼型Pd催化劑,2012.05,中國ZL200910304443.9
4. 梁長海,李闖,陳霄,邵正峰,肖子輝,一種利用塑料油生產汽柴油的工藝, 2012.11,中國,ZL201010172161.0
5. 梁長海,陳霄,李苗,管婧超,“一種甲烷化催化劑及其應用”,中國專利公開CN102327769A,2011
6. 梁長海,陳霄,李闖,汪鐳, “一種利用煤焦油生產汽柴油的方法”, 中國專利申請201210148933.5,2012
7. 梁長海,陳霄,李闖,汪鐳, “一種含硅金屬間化合物加氫脫氯催化劑、製備方法及應用”, 中國專利申請201210386990.8,2012
8. 梁長海,李闖,陳霄,汪鐳,“利用塑料油、煤焦油、乙烯焦油或輪胎油混合煉製生產汽柴油的方法”,中國專利申請201210264707.4,2012
9. 梁長海,李闖,陳霄,肖子輝,汪鐳,“一種廢潤滑油資源化利用的方法”,中國專利申請201210265279.7,2012
10. 梁長海,李闖,陳霄,肖子輝,邵正峰, “一種利用橡膠油生產汽柴油的新技術”, 中國專利公開CN102676220A,2012
11. 梁長海,李闖,陳霄,肖子輝,邵正峰, “一種常溫製備金屬膠體的方法”, 中國專利公開CN102672196A,2012
12. 梁長海,汪鐳,陳霄,肖子輝,邵正峰,“一種利用植物油生產可再生汽柴油的方法”,中國專利公開CN102250634A,2011
13. 梁長海,李闖,陳霄,肖子輝,邵正峰,“一種利用廢潤滑油生產汽柴油的方法”,中國專利公開CN102226104A,2011
14. 梁長海,李闖,陳霄,邵正峰,肖子輝,“一種利用塑料油生產汽柴油的方法”,中國專利公開CN102226103A,2011
15. 梁長海,李闖,陳霄,邵正峰,肖子輝,“一種頁岩油催化提質技術”,中國專利公開CN101899326A,2010、
16. 梁長海,許春建,李闖,陳霄,肖子輝,“一種催化加氫製備高檔樹脂的方法”,中國專利公開CN102633941A,2012
17. 梁長海,徐彬,蕭錦誠,汪鐳,陳霄,邵正峰,肖子輝,“從生物性油脂製備燃料的方法”,中國專利申請201110425819.9;中國台灣專利申請101104242,2011;PCT/CN2012/000013, 2012