王哲明

1979-1983年，北京大學理學學士（放射化學）

1985-1989年，福州大學理學碩士（物理化學）

1993-1996年，北京大學理學博士（物理化學）

1983-1985年，化工部青島勞動保護研究所，助理工程師

1889-1993年，福州大學化學系，講師

1996-至今，北京大學化學與分子工程學院，博士生導師（2005年），教授（2006年）

2002-2003年，日本岡崎國立共同研究機構，分子科學研究所，日本文部省COE訪問副教授

主講課程：高等無機化學（研究生課），結構與物性（物理專業本科生），中級無機化學實驗（化學專業本科生）

1． 磁電阻材料的化學製備和性質；

2． 分子間相互作用和分子組裝；超分子聚集體的形和拓撲；

3． 磁性、電性功能材料的晶體工程。

在鈣鈦礦型稀土錳基氧化物磁電阻材料研究中，採用化學法從摻雜和複合兩個方面考察對磁電阻性能及其機理的影響。獲得了如MR得到顯著增強，MR對外加磁場的靈敏度的明顯改善，MR的符號可以得到調節等結果，這些結果對於磁電阻材料的實際應用具有重要意義。有關論文發表在Phys. Rev. B, Appl. Phys. Lett. 等期刊上。

在具有新穎拓撲特性的配位聚合物及其磁性、多鹵素與生物氮鹼組裝的納米結構、多核稀土配合物、新的分子間相互作用類型等方面的研究中得到了一系列的研究成果，有關工作發表在New J. Chem., J. Am. Chem. Soc., J Chem. Soc. Dalton Trans., CrystEngComm等期刊上。

研究工作得到國家科技部國家重點基礎研究發展規劃項目(G1998061310)、國家自然科學基金委青年基金(29701001)資助。

2008

Liu T, Zhang YJ, Wang ZM*, Gao S*, “A 64-nuclear cubic cage incorporating propeller-like FeIII8 apices and HCOO- edges”, J. Am. Chem. Soc. 2008, 130, 10500-10501.

Yao JY, Xiao Z, Gan LB*, Yang DZ, Wang ZM*, “Towards the Rational Synthesis of Norfullerenes. Controlled Deletion of One Carbon Atom from C60 and Preparation of 2,5,9-Trioxo-1-nor(C60-Ih)[5,6]fullerene C59(O)3 Derivatives”, Org. Lett. 2008, 10, 2003-2006.

Yang XB, Gan LB*, Wang ZM*, “Controlled regio- and chemoselective addition of isothiocyanate to the dione moiety of a cage-opened fullerene-mixed peroxide derivative”, Chem. Commun. 2008, 1980-1982.

Liu T, Yang YF, Wang ZM*, Gao S*, “Two diammonium copper azides with similar layerlike magnetic substructures made of chains of serially connected Cu6 rings show cation-modulated magnetism”, Chem. Asian J. 2008, 3, 950-957.

Wang XY, Wang ZM, Gao S*, “Detailed magnetic studies on Co(N-3)2(4-acetylpyridine)2: a weak-ferromagnet with a very big canting angle”, Inorg. Chem. 2008, 47, 5720-5726.

Liu T, Wang BW, Chen YH, Wang ZM*, Gao S*, “Syntheses, structures and magnetic properties of two mixed-valent disc-like hepta-nuclear compounds of [(FeIIFe6III)(tea)6](ClO4)2 and [(MnII3MnIII4)(nmdea)6(N3)6]·CH3OH (tea = N(CH2CH2O)33-, nmdea = CH3N(CH2CH2O)22-)”, Zeit. Anorg. Allge. Chem. 2008, 634, 778-783.

Wang XY, Wang ZM, Gao S*, “Constructing magnetic molecular solids by employing three-atom ligands as bridges”, Chem. Commun. 2008, 281-294.

2007

Wang ZM*, Zhang XY, Batten SR*, Kurmoo M*, Song Gao*, “[CH3NH2(CH2)2NH2CH3][M2(HCOO)6] (M=MnII and CoII): Weak ferromagnetic metal formate frameworks of unique binodal 6-connected (412·63)(49·66) topology, templated by a diammonium cation”, Inorg. Chem. 2007, 46, 8439-8441.

Xu HB, Wang BW, Pan F, Wang ZM, Gao S*,, “Stringing oxo-centered trinuclear [MnIII3O] units into single-chain magnets with formate or azide linkers”, Angew. Chem. Int. Ed. 2007, 46, 7388-7392.

Xiao Z, Yao JY, Yang DZ, Wang FD, Huang SH, Gan LB,* Jia ZS, Jiang ZP, Yang XB, Zheng B, Yuan G, Zhang SW, Wang ZM*, “Synthesis of [59]Fullerenones through Peroxide-Mediated Stepwise Cleavage of Fullerene Skeleton Bonds and X-ray Structures of Their Water-Encapsulated Open-Cage Complexes”, J. Am. Chem. Soc. 2007, 129, 16149-16162.

Pan F, Wang ZM, Gao S*, “Magneto-Structural Correlation in a Series of Bimetallic Alternating Chain Complexes of [CrIIIL(CN)4]n[MnIII(salpn)]n·nSolvents (L = 2,2’-bipy or 9,10-phen, salpn = Substituted Salicyldehyde, Solvents = Water and Methanol), Inorg. Chem.2007, 46, 10221-10228.

Wang XT, Wang ZM, Gao S*, “Honeycomb Layer of Cobalt(II) Azide Hydrazine Showing Weak Ferromagnetism”, Inorg. Chem.2007, 46, 10452-10454.

Wang ZM*, Zhang B, Zhang YJ, Kurmoo M, Liu T, Gao S*, Kobayashi, H*, “A family of porous magnets, [M3(HCOO)6] (M = Mn, Fe, Co and Ni)”, Polyhedron 2007, 26, 2207-2215.

Wang ZM*, Zhang YJ, Liu T, Kurmoo M, Gao S*, “[Fe3(HCOO)6]: A permanent porous diamond framework displaying H-2/N-2 adsorption, guest inclusion, and guest-dependent magnetism”, Adv. Funct. Mater. 2007, 17, 1523-1536.

Xu HB, Wang ZM, Liu T, Gao S*, “Synthesis, structure, and magnetic properties of (A)[FeIII(oxalate)Cl2] (A = alkyl ammonium cations) with anionic 1D [FeIII(oxalate)Cl2]- chains”, Inorg. Chem. 2007, 46, 3089-3096.

Wang XY, Wang ZM, Gao S*, “A pillared layer MOF with anion-tunable magnetic properties and photochemical [2+2] cycloaddition”, Chem. Commun. 2007, 1127-1129.

Zhang W, Zhao F, Liu T, Yuan M, Wang ZM*, Gao S*, “Spin crossover in a series of iron(II) complexes of 2-(2-alkyl-2H-tetrazol-5-yl)-1,10-phenanthroline: Effects of alkyl side chain, solvent, and anion”, Inorg. Chem. 2007, 46, 2541-2555.

Zhang B*, Wang ZM*, Kurmoo M, Gao S, Inoue K, Kobayashi H*, “Guest-induced chirality in the ferrimagnetic nanoporous diamond framework Mn3(HCOO)6”, Adv. Funct. Mater. 2007, 17, 577-584.

Zhu WH, Wang ZM*, Gao S*, “Two 3D porous lanthanide-fumarate-oxalate frameworks exhibiting framework dynamics and luminescent change upon reversible de- and rehydration”, Inorg. Chem. 2007, 46, 1337-1342.

Wang ZM*, Zhang B, Inoue K, Fujiwara H, Otsuka T, Kobayashi H*, Kurmoo M, “Occurrence of a rare 49·66 structural topology, chirality, and weak ferromagnetism in the [NH4][MII(HCOO)3] (M = Mn, Co, Ni) frameworks”, Inorg. Chem. 2007, 46, 437-445.

2006

Zhang YZ, Wang ZM, Gao S*, “Three-dimensional heterometallic chiral Cr-Mn compound constructed by cyanide and dicyanamide bridges”, Inorg. Chem. 2006, 45, 10404-10406.

Liu T, Chen YH, Zhang YJ, Wang ZM*, Gao S*. “NaCl-type frameworks of [M(pyrazine)2NO2]ClO4 (M) Co, Cu), the first examples containing mu 1,3-nitrito bridges showing antiferromagnetism”, Inorg. Chem. 2006, 45, 9148-9150.

Wang ZM*, Zhang YJ, Kurmoo M*, Liu T, Vilminot S, Zhao B, Gao S*, “[Zn3(HCOO)6]: A porous diamond framework conformable to guest inclusion”, Aust. J. Chem. 2006, 59, 617-628.

He Z, Wang ZM*, Gao S, Yan CH*, “Coordination polymers with end-on azido and pyridine carboxylate N-oxide bridges displaying long-range magnetic ordering with low dimensional character”, Inorg. Chem. 2006, 45, 6694-6705.

Zhang YZ, Wernsdorfer W, Pan F, Wang ZM, Gao S*, “An azido-bridged disc-like heptanuclear cobalt(II) cluster: towards a single-molecule magnet”, Chem. Commun. 2006, 3302-2006.

Zhang YZ, Wang ZM, Gao S*, “Heterometallic Cr-Mn complexes containing cyanide and oxalate bridges’, Inorg. Chem. 2006, 45, 5447-5454.

Liu T, Zhang YJ, Wang ZM*, Gao S*, “Two chain compounds of [M(N3)2(HCOO)][(CH3)2NH2] (M = Fe and Co) with a mixed azido/formato bridge displaying metamagnetic behavior”, Inorg. Chem. 2006, 45, 2782-2784.

Zhu WH, Wang ZM*, Gao S*, “A 3D porous lanthanide-fumarate framework with water hexamer occupied cavities, exhibiting a reversible dehydration and rehydration procedure”, Dalton Trans. 2006, 765-768.

Wang XY, Wang L, Wang ZM, Gao S*, “Solvent-tuned azido-bridged Co2+ layers: Square, honeycomb, and Kagome”, J. Am. Chem. Soc. 2006, 128, 674-675.

Stride JA*, Kurmoo M, Wang ZM, “Investigations of guest-modulated ordering temperatures in open-framework 3D porous magnets”, Phys. B. Conds. Matter 2006, 385, 465-467.

Cui HB, Wang ZM, Takahashi K, Okano Y, Kobayashi H*, Kobayashi A, “Ferroelectric porous molecular crystal, [Mn3(HCOO)6](C2H5OH), exhibiting ferrimagnetic transition”, J. Am. Chem. Soc. 2006, 128, 15074-15075.

Huang QC*, Wang ZM, Chu QL, Zhu SZ*, “Crystal structure of a supramolecular complex formed between 1-bromo-2-iodo-tetrafluoroethane and N,N,N ',N '-tetramethyl-ethylenediamine”, J. Incl. Phen. Macrocyc. Chem. 2006, 54 177-180.

Zhang B*, Wang ZM, Zhang Y, Takahashi K, Okano Y, Cui HB, Kobayashi H*, Inoue K, Kurmoo M, Pratt FL, Zhu DB*, “Hybrid organic-inorganic conductor with a magnetic chain anion: k-BETS2[FeIII(C2O4)Cl2] [BETS = bis(ethylenedithio)tetraselenafulvalene]”, Inorg. Chem. 2006, 45, 3275-3280.

2005

Chang F, Wang ZM*, Sun HL, Gao S*, Wen GH, Zhang XX, “{[Cu2(bpdado)2(H2O)2]·H2O}n: A 1D nanotubular coordination polymer with wall made of edge-sharing hexagons, where bpdado=2,2 '-bipyridine-3,3 '-dicarboxylate-1,1 '-dioxide”, Dalton Trans. 2005, 2976-2978, inside front cover

He Z, Wang ZM*, Yan CH*, “Ligand-controlled dimensionality: 1D, 2D and 3D Gd(III) coordination polymers based on SO42- and pyridine carboxylate N-oxide ligands”, CrystEngComm. 2005, 7, 143-150.

He Z, Gao EQ, Wang ZM*, Yan CH*, Kurmoo M, “Coordination polymers based on inorganic lanthanide(III) sulfate skeletons and an organic isonicotinate N-oxide connector: Segregation into three structural types by the lanthanide contraction effect”, Inorg. Chem. 2005, 44, 862-874.

Wang ZM*, Zhang B, Kurmoo M, Green MA, Fujiwara H, Otsuka T, Kobayashi H*, “Synthesis and characterization of a porous magnetic diamond framework, Co3(HCOO)6, and its N2 sorption characteristic”, Inorg. Chem. 2005, 44, 1230-1237.

Wang XY, Wang L, Wang ZM, Su G, Gao S*, “Coexistence of spin-canting, metamagnetism, and spin-flop in a (4,4) layered manganese azide polymer”, Chem. Mater. 2005, 17, 6369-6380.

Zhang YZ, Wei HY, Pan F, Wang ZM, Chen ZD,* Gao S*, “Two molecular tapes consisting of serial or parallel azido-bridged eight-membered copper rings”, Angew. Chem. Int. Ed. 2005, 44, 5841-5846.

Zhang B*, Wang ZM, Fujiwara H, Kobayashi H*, Kurmoo M, Inoue K, Mori T, Gao S, Zhang Y, Zhu DB*, “Tetrathiafulvalene [FeIII(C2O4)Cl2]: An organic-inorganic hybrid exhibiting canted antiferromagnetism”, Adv. Mater. 2005, 17, 1988-1991.

Cui HB, Takahashi K, Kano Y, Kobayashi H*, Wang ZM, Kobayashi A, “Dielectric properties of porous molecular crystals that contain polar molecules”, Angew. Chem. Int. Ed. 2005, 44, 6508-6512.

Zhang YZ, Gao S,* Wang ZM, Su G, Sun HL, Pan F, “Rational synthesis and magnetic properties of a family of low-dimensional heterometallic Cr-Mn complexes based on the versatile building block [Cr(2,2 '-bipyridine)(CN)4]-”, Inorg. Chem. 2005, 44, 4534-4545.

Sun HL, Wang ZM, Gao S*, “Synthesis, crystal structures, and magnetism of cobalt coordination polymers based on dicyanamide and pyrazine-dioxide derivatives”, Inorg. Chem. 2005, 44, 2169-2176.

Wang XY, Wei HY, Wang ZM, Chen ZD*, Gao S*, “Formate - The analogue of azide: Structural and magnetic properties of M(HCOO)2(4,4 '-bpy)·nH2O (M=Mn, Co, Ni; n=0, 5)”, Inorg. Chem. 2005, 44, 572-583.

Before 2005 (selected)

Wang ZM*, Zhang B, Otsuka T, Inoue K, Kobayashi H*, Kurmoo M, “Anionic NaCl-type frameworks of [MnII(HCOO)3-], templated by alkylammonium, exhibit weak ferromagnetism”, Dalton Trans. 2004, 2209-2216.

Wang ZM*, Zhang B, Fujiwara H, Kobayashi H*, Kurmoo M, “Mn3(HCOO)6: a 3D porous magnet of diamond framework with nodes of Mn-centered MnMn4 tetrahedron and guest-modulated ordering temperature”, Chem. Commun. 2004, 416-417.

He Z, He C, Wang ZM*, Gao EQ, Liu Y, Yan CH*, “Self-assembly of molecular squares based on easy-to-prepare multidentate Schiff base ligands”, Dalton Trans. 2004, 502-504.

He Z, He C, Gao EQ, Wang ZM*, Yang XF, Liao CS, Yan CH*, “Lanthanide-transition heterometallic extended structures with novel orthogonal metalloligand as building block”, Inorg. Chem. 2003, 42, 2206-2208.

Wang ZM, Sun BW, Luo J, Gao S, Liao CS, Yan CH*, Li Y, “Bimetallic sandwiches assembled with chelated Cu/Zn cations and manganese dicyanamide polymeric ladders”, Polyhedron, 2003, 22, 433-439.

Xu G, Wang ZM*, He Z, Lu Z, Liao CS, Yan CH*, “Synthesis and structural characterization of nonanuclear lanthanide complexes”, Inorg. Chem. 2002, 41, 6802-6807.

Cheng YJ, Wang ZM*, Liao CS, Yan CH*, “Novel sheet-like supramolecular architectures constructed from infinite hydrogen-bonded, protonated adenine water halide and polyiodide ribbons”, New J. Chem. 2002, 26, 1360-1364.

Wang ZM, Sun BW, Luo J, Gao S, Liao CS, Yan CH*, Li Y, “Bimetallic sheet and 3D threefold interpenetrating diamond-like network constructed by chelate Cu cations and Mn dicyanamide polymeric chains. Synthesis, crystal structure, and magnetism of [CuL2][Mn(dca)4] (L = ethylenediamine or 1,3-diaminopropane; dca = dicyanamide N(CN)2-)”, Inorg. Chim. Acta 2002, 332, 127-134.

Wang ZM, Cheng YJ, Liao CS, Yan CH*, “The first supramolecular architectures assembled by infinite hydrogen-bonded, protonated nucleobase-water ribbons and unusual polyiodide frameworks”, CrystEngComm. 2001, art no. 50.