郭新聞

分子篩催化

雜原子分子篩的合成及其催化性能研究

多環芳烴擇形催化製備功能材料單體

環境友好催化與催化新材料

已申請發明專利5項，發表論文被SCI收錄79篇，EI收錄72篇，與其他老師合寫專著綠色石化技術的科學與工程基礎的一章。

在讀碩士生14名，在讀博士10名

已畢業碩士博士人數：畢業碩士8名，博士2名。

1985年9月-1989年7月：

大連理工大學化工學院高分子材料系本科生

1989年9月-1994年9月：

大連理工大學化工學院工業催化系博士生（碩博連讀）1994年9月-1996年5月，大連理工大學化工學院工業催化系講師

1996年5月-2001年3月：

大連理工大學化工學院工業催化系副教授

2001年3月-至今：

大連理工大學化工學院工業催化系教授

1995年9月-2000年9月；

碳資源綜合利用部門開放實驗室副主任

2000年9月-至今：

精細化工國家重點實驗室副主任。

2001年4月-2002年4月：

賓夕法尼亞州立大學訪問教授（國家公派，21世紀教育振興行動計劃）

2004年11月-2005年3月：

賓夕法尼亞州立大學訪問教授.

2005年3月-至今：

大連理工大學化工學院副院長、黨委書記

中國化學會催化專業委員會委員

石油學報（石油加工）編委

催化基礎國家重點實驗室學術委員會委員

大連理工大學學術委員會委員

鈦硅分子篩的合成和丙烯環氧化反應

主要採用廉價模板劑合成鈦硅沸石，並用於丙烯環氧化制環氧丙烷。該領域曾得到一項國家自然科學基金委‘九五’ 重大項目子課題“環氧丙烷鈦硅沸石催化劑及反應過程的基礎研究”（29792071），在2001年4月國家自然科學基金委組織的結題驗收中，此課題被評為特優，其技術水平被認定為國際先進。該課題主要研究：鈦硅沸石的水熱合成，二次合成法製備鈦硅沸石，丙烯環氧化制環氧丙烷催化劑的研製和評價。與國內外同行相比，特色是：

實現了用廉價TPABr代替TPAOH作為模板劑水熱合成鈦硅沸石，建立了簡便的合成體系，模板劑量減少至接近理論值，製備重複性很好，使鈦硅沸石成為工業沸石。

從丙烯環氧化主副反應都是強放熱、環氧丙烷（PO）是目的產物也是副反應乃至引起催化劑失活物種的起始原料的特點，研製成功負載型小球催化劑。本人在本課題中承擔重要的研究和管理工作，輔助指導博士生兩名，碩士生2名，發表文章50餘篇，SCI收錄十餘篇，並申請專利3項，參加編寫專著1本。現在，“300噸/年丙烯環氧化法生產環氧丙烷工業中間試驗”已在中國石油天然氣集團公司立項，工業中試正在進行中，本人為主要參加者。

新催化材料

主要研究丙烯環氧化和環己酮氨氧化新催化材料、低碳烴類氣相氧化新型催化材料，被列入國家重點基礎研究（973）項目子課題和教育部重點科技項目。

擇形催化

主要研究多環芳烴的烷基化，以萘及聯苯烷基化生成2，6-二烷基萘及4，4-二烷基聯苯為主，這些產物是合成功能塑料、纖維、聚合物及液晶的重要單體，日益受到關注。烷基化試劑中，以甲醇為佳，因為進一步氧化條件溫和、原子經濟性高。但甲醇分子小，擇形催化難度高。本人在美國賓夕法尼亞州立大學做訪問學者期間，取得了突破性進展，4，4-二烷基聯苯選擇性達到90%（文獻最好結果為65%）。已完成論文四篇，並在美國ACS會議上宣讀。

Shape selective methylation of 4-methylbiphenyl or naphthalene with methanol over modified HZSM-5

1. Xinwen Guo,Jianping Shen,Lu Sun,Chunshan Song,Xiangsheng Wang,Effects of SiO2/Al2O3,Mg modification and hydrothermal treatment on the catalytic activity of HZSM-5 zeolites in the methylation of 4-methylbiphenyl with methanol,Applied Catalysis A,General,2004,261:183-189.

2. Xinwen Guo,Jianping Shen,Chunshan Song,Xiangsheng Wang,Effects of SiO2/Al2O3,MgO modification and hydrothermal treatment on shape-selective methylation of 4-methylbiphenyl with methanol over HZSM-5 zeolites,Proceedings: 14th International zeolite conference. Editors: E. Van Steen et al. ISBN 0-958-46636-X,25-30 April 2004,Cape Town,South Africa,P2247-2254.

3. Xinwen Guo,Jianping Shen,Lu Sun,Chunshan Song,Xiangsheng Wang， Shape-selective methylation of 4-methylbiphenyl to 4,4’-dimethylbiphenyl over HZSM-5 modified with metal oxide of MgO,CaO,SrO,BaO and ZnO,Catalysis Letters,2003,87（1-2）：25-29.

4. Xinwen Guo,Jianping Shen,Lu Sun,Chunshan Song,Xiangsheng Wang,Effect of hydrothermal treatment conditions on the catalytic activity of HZSM-5 zeolites in the methylation of 4-methylbiphenyl,Catalysis Letters,2003,87（3-4）：159-166.

5. Xinwen Guo,Xiangsheng Wang,Jianping Shen,Chunshan Song,Shape-selective synthesis of 4,4’-dimethylbiphenyl over hydrothermally treated HZSM-5 catalysts,Chinese Journal of Catalysis,2003,24⑼：647-648.

6. Xinwen Guo,Xiangsheng Wang,Jianping Shen,Lu Sun,Chunshan Song,Methylation of 4-methylbiphenyl with methanol over metal oxide modified HZSM-5 zeolite catalyst,Chinese Journal of Catalysis，2003，24⑸：333-337。

7. Xinwen Guo,Jianping Shen,Chunshan Song,Xiangsheng Wang,Shape Selective Methylation of 4-Methylbiphenyl with Methanol over MgO/HZSM-5 Catalyst. Am. Chem. Soc. Div. Fuel Chem. Prepr.,2003,48 ⑵，902-903.

8. Xinwen Guo,Jianping Shen,Lu Sun,Chunshan Song,Xiangsheng Wang,Reactivity of 4,4'-Dimethylbiphenyl with Methanol over Modified HZSM-5 Catalysts. Am. Chem. Soc. Div. Petrol. Chem. Prepr.,2003,48 ⑷，280-281.

9.Xinwen Guo,Jianping Shen,Lu Sun,Chunshan Song,Xiangsheng Wang. Shape-selective Methylation of 4-Methylbiphenyl with Methanol over Metal Oxide Modified HZSM-5 Prepared by Ion-Exchange Method. Am. Chem. Soc. Div. Petrol. Chem. Prepr.,2003,48 ⑷，286-287.

10. Xinwen Guo,Xiangsheng Wang,Jianping Shen,Lu Sun,Chunshan Song,Synthesis of 4,4-dimethylbiphenyl through shape-selective methylation of 4-methylbiphenyl with methanol I. Comparison of MgO modified and hydrothermally treated HZSM-5 zeolite catalysts,ACTA PETROLEI SINICA(PETROLEUM PROCESSING SECTION),2004,20⑴： 6-11.

11. Xinwen Guo,Xiangsheng Wang,Jianping Shen,Lu Sun,Chunshan Song,Shape-selective methylation of 4-methylbiphenyl with methanol into 4,4-dimethylbiphenyl Ⅱ. Effects of zeolite type,the SiO2/Al2O3 mol ratios and phosphorus modification,ACTA PETROLEI SINICA (PETROLEUM PROCESSING SECTION),2004,20⑶： 37-42.

12. Yanan wang,Xinwen Guo,Xiangsheng Wang,Development of Shape-selective alkylation of biphenyl to 4,4’-dialkybiphenyl,Chemical Industry and Engineering Progress,2004,23⑴： 51-54.

13. Yin Weishan,Xinwen Guo,Xiangsheng Wang,Development of shape-selective methylation of naphthalene into 2,6-dimethylnaphthalene,Petrochemical Technology,2003,32⑾： 1007-1011.

14. Xinwen Guo,Xiangsheng Wang,Jianping Shen,Chunshan Song,Shape selective synthesis of 4,4’-dimethylbiphenyl over modified ZSM-5 catalysts,Catalysis Today,2004,93-95:411-416.

15. Xinwen Guo,Xiangsheng Wang,Jianping Shen,Chunshan Song,Methylation performance of 4-methylbiphenyl with methanol over MgO modified HZSM-5,Petrochemical Technology,2003,32: 334-336.

Gas-Phase Epoxidation of Propylene in the presence of H2 and O2 over Ag/TS-1

1. Ruipu Wang,Xinwen Guo,Xiangsheng Wang,Jingquan Hao,Propylene epoxidation over silver supported on titanium silicalite zeolite,Catalysis Letters,2003,90（1-2）：57-63.

2. Ruipu Wang,Jingquan Hao,Xinwen Guo,Xiangsheng Wang,Highly effective propylene epoxidation with hydrogen-oxygen mixture over Ag/TS-1 catalysts,Chinese Journal of Catalysis,2003,24⑸：319-320.

3. Ruipu Wang,Xinwen Guo,Xiangsheng Wang,Jingquan Hao,Gang Li,Jinghai Xiu,Effects of preparation conditions and reaction conditions on the epoxidation of propylene with molecular oxygen over Ag/TS-1 in the presence of hydrogen,Applied Catalysis A,General,2004,261: 7-13.

4. Ruipu Wang,Xinwen Guo,Xiangsheng Wang,Jingquan Hao,Yingwu Li,Synthesis of propylene oxide by gas-phase propylene epoxidation over Ag/TS-1 prepared with different precipitators,Chinese Journal of Catalysis,2004,25⑴：55-59.

5. Ruipu Wang,Jingquan Hao,Xinwen Guo,Xiangsheng Wang,Characterization and gas-phase epoxidation performance of Ag/TS-1 prepared with carbonate as precipitators Prepr. Pap.-Am.Chem.Soc.,Div. Pet. Chem. 2003,48⑷，264.

6. Jingquan Hao,Ruipu Wang,Xinwen Guo,Xiangsheng Wang,Gas-phase epoxidation of propylene over La-promoted Ag/TS-1 catalysts,Advances in Fine petrochemicals (China),2003,4⑻： 1-4.

7. Ruipu Wnag,Hao Jingquan,Xinwen Guo,Xiangsheng Wang,Xuewu Liu,Propylene epoxidation over Ag/TS-1 catalysts,Proceedings: 14th International zeolite conference. Editors: E. Van Steen et al. ISBN 0-958-46636-X,25-30 April 2004,Cape Town,South Africa,P2632-2638.

8. Chuanfu Wang,Xinwen Guo,Xiangsheng Wang,Ruipu Wang,Jingquan Hao,Preparation of Ag/TS-1 in microemulsion and its catalytic properties in the gas-phase propylene epoxidation,Prep. Pap. –Am. Chem. Soc.,Div. Pet. Chem. 2004,49⑴： 29-31.

9. Chuanfu Wang,Xinwen Guo,Xiangsheng Wang,Ruipu Wang,Jingquan Hao,Gas-phase propylene epoxidation over Ag/TS-1 prepared in W/O microemulsion,Catalysis Letters,2004,96（1-2）： 79-85.

10. Xinwen Guo,Ruipu Wang,Xiangsheng Wang,Jingquan Hao,Effects of preparation method and precipitator on the propylene epoxidation over Ag/TS-1 in the gas-phase,Catalysis Today,2004,93-95: 211-216.

11. Ruipu Wang,Xinwen Guo,Xiangsheng Wang,Jingquan Hao,Gas-phase epoxidation of propylene over Ag/Ti-containing catalysts,Catalysis Today,2004,93-95: 217-222.

12. Ruipu Wang,Jingquan Hao,Xinwen Guo,Xiangsheng Wang,Direct synthesis of propylene oxide by gas phase of propylene over Ag/TS-1,ACTA PETROLEI SINICA (PETROLEUM PROCESSING SECTION),2004,20⑷： 44-50.

Olefins Reduction in FCC gasoline

1. Peiqing Zhang,Xiangsheng Wang,Xinwen Guo,Hongchen Guo,Leping Zhao,Yongkang Hu,Characterization of modified nanoscale ZSM-5 seolite and its application in the olefins reduction in FCC gasoline,Catalysis Letters,2004,92（1-2）： 63-68.

2. Fu Yang,Xiangsheng Wang,Yihui Liu,Xinwen Guo,et al.,Characterization of catalyst for upgrading DCC gasoline and its reactivity evaluation,Journal of Dalian University of Technology,2004,44⑴： 35-38.

Synthesis,Characterization and Catalytic properties of titanium silicalites

1. Xuewu Liu,Xiangsheng Wang,Xinwen Guo,Gang Li,Regeneration of Lamina TS-1 catalyst in the epoxidation of propylene with hydrogen peroxide,Catalysis Letters,2004,97（3-4）： 223-229.

2. Min Liu,Xinwen Guo,Xiangsheng Wang,Changhai Liang,Can Li,Effect of n (SiO2/B2O3） in the precursor on chemical physics properties of Ti-ZSM-5 synthesized by gas-solid method,Catalysis Today,2004,93-95:659-664.

3. Xuewu Liu,Xiangsheng Wang,Xinwen Guo,Gang Li,Haisheng Yan,Effect of solvent on the propylene epoxidation over TS-1 catalyst,Catalysis Today,2004,93-95:505-509.

4. Weiguo Cheng,Xiangsheng Wang,Gang Li,Xinwen Guo,Highly effective epoxidation of propylene in the TS-1/urea/hydrogen peroxide system,Chinese Journal of Catlysis,2004,25⑺： 513-514.

5. Min Liu,Xinwen Guo,Xiangsheng Wang,Changhai Liang,Can Li,The synthesis of Ti-ZSM-5 from B-ZSM-5 precursor for epoxidation of propylene,Acta Petrolei Sinica (Petroleum Processing section),2004，20⑷：20-25.

6. Jimen Meng,Gang Li,Xinwen Guo,Xiangsheng Wang,Intergrate reaction of isopropanol oxidation and epoxidation of propylene,Acta Petrolei Sinica (Petroleum Processing section),2004，20⑷：38-43.

7. Xiangsheng Wang,Xinwen Guo,Gang Li,Synthesis of titanium silicalite（TS-1）from the TPABr system and its catalytic properties for epoxidation of propylene， Catal Today，2002,74（1-2）：65~75。

8. Xinwen Guo,Xiangsheng Wang,Min Liu,etc.,Epoxidation of propylene with dilute hydrogen peroxide over titanium silicalite containing trace aluminum，Catalysis Letters， 2002，81（1-2）：125-130。

9. Liqin Wang,Xiangsheng Wang,Xinwen Guo,Gang Li,Yongying Chen,Synthesis of titanium silicalite-1 in the presence of Tween 40,Chinese Journal of Catalysis,2003,24⑶： 161-162.

10. Xiangsheng Wang,Xinwen Guo,Synthesis,characterization and catalytic properties of low cost titanium silicalites,Catal. Today,1999,51:177.

11. Gang Li,Xinwen Guo,Xiangsheng Wang,Qi Zhao,etc.,Synthesis of titanium silicalites in different template systems，　Appl. Catal.A: General,1999,185:11-18.

12. Fazhi Zhang,Xinwen Guo,Xiangsheng Wang,etc.,Preparation and characterization of titanium-containing MFI from highly silicious ZSM-5: Effects of precursors synthesized with different templates,Materials Chemistry and Physics,1999,60: 215.

13. Fazhi Zhang,Xinwen Guo,Xiangsheng Wang,etc.,Preparation of titanium-containing zeolites with MEL structure from B-ZSM-11 and their characterization,Appl. Catal. A: General,2000,192⑵： 157-163.

14. Qi Zhao,Xinhe Bao,Xiuwen Han,Liwu Lin,Xinwen Guo,Gang Li,Xiangsheng Wang,Studies on the crystallization process of titanium silicalite (TS-1） synthesized using tetra-propyl-ammonium bromide as a template,Materials Chemistry and Physics,2000,66⑴： 41-50.

15. Qi Zhao,Xinhe Bao,Xiuwen Han,Liwu Lin,Xinwen Guo,Gang Li,Xiangsheng Wang,Studies on superoxide O2- species on the interaction of TS-1 zeolite with H2O2,Journal of Molecular A Chemical,2000,157（1-2）：265-268.

16. Gang Li,Xiangsheng Wang,Xinwen Guo,Song Liu,Qi Zhao,Xinhe Bao,Liwu Lin,Titanium species in titanium silicalite TS-1 prepared by hydrothermal method,Materials Chemistry and Physics,2001,71⑵：195-201.

17. Xinwen Guo，Xiangsheng Wang， Min Liu，Yongying Chen，Gang Li， Jinghai Xiu， Epoxidation of propylene with dilute hydrogen peroxide over titanium silicalite containing trace aluminum,Stud. Surf. Sci. Catal.，2001，135：165

18. Fazhi Zhang,Xinwen Guo,Xiangsheng Wang,Gang Li,The active sites in different TS-1 zeolites for propylene epoxidation studied by ultraviolet resonance Raman and ultraviolet visible absorption spectroscopies,Catalysis letters,2001,72（3-4）：235-239. 19. Xiangsheng Wang,Xinwen Guo,Yihua Zhang,Honglin Wang,Synthesis，characterization and catalytic properties of TS/ TiO2 nano-structured composite materials The 4th green chemistry and engineering proceedings,2000,6,p91,oral,Washington,USA.

20. Gang Li,Xinwen Guo,Xiangsheng Wang,Zhuohua Zhou,Qi,Zhao,etc.,A kind of inactive titanium species in titanium silicalite,Chinese Journal of Catalysis，1999，20⑵，99-100.

21. Yihua Zhang,Xiangsheng Wang,Xinwen Guo,Song Liu,Synthesis of titanosilicalite using titanium tetrachloride as titanium source，Chinese Journal of Catalysis,2000,21⑶：197-198.

22. Yihua Zhang,Xiangsheng Wang,Xinwen Guo,Yongying Chen,Synthesis of titanosilicalites TS-1 with mixture of tetrabutyl orthosilicalite (TBOT) and titanium tetrachloride (TiCl4） as the titanium source,Chinese Journal of Molecular Catalysis，2001,15⑵：149.

23. Liqin Wang,Xiangsheng Wang,Xinwen Guo,Gang Li,Jinghai Xiu,Song Liu,Study on crystallization kinetics for synthesis of TS-1 and its catalytic performance,Chinese Journal of Catalysis,2003,24⑵：132-136.

24. Xiangsheng Wang,Gang Li,Haisheng Yan,Xinwen Guo,Epoxidation of propylene in fixed bed reactor using supported titanium silicalite catalyst,Stud. Surf. Sci. Catal,2001,135: 273.

25. Gang Li,Xinwen Guo,Xiangsheng Wang,Recent process of synthesis of propylene oxide,Chemical Process (China),1999,18⑴，8-10.

26. Gang Li,Xinwen Guo,Xiangsheng Wang,Catalytic properties of titanium silicalites synthesized by hydrothermal method,ACTA PETROLEI SINICA (Petroleum Processing Section),1999，15⑸： 73-76.

27. Fazhi Zhang,Xinwen Guo,Xiangsheng Wang,Zhuohua Zhou,Preparation of Ti-ZSM-5 zeolites by gas-solid isomorphous replacement and their catalytic performance,Journal of Molecular Catalysis (China),1999，13：121-126.

28. Fazhi Zhang,Xinwen Guo,Xiangsheng Wang,Epoxidation of propylene with hydrogen peroxide over Ti-ZSM-5 prepared by gas-solid isomorphous substitution,ACTA PETROLEI SINICA (Petroleum Processing Section),1999，15⑷：76-80.

29. Fazhi Zhang,Xinwen Guo,Xiangsheng Wang,et al.,Preparation of Ti-Beta zeolite by gas-solid interaction,I. Effect of dealumination of the zeolite precursor,Chinese Journal of Catalysis,1999，20⑷：467-470.

30. Fazhi Zhang,Xinwen Guo,Xiangsheng Wang,Song Liu,Preparation of titanium-containing Mordenites by gas-solid reaction,Journal of Molecular Catalysis (China),1999，13⑹：461-463..

31. Gang Li,Xinwen Guo,Xiangsheng Wang,Guangyan Li,Study on crystallization kinetics of titanium silicalite,Chinese Journal of Catalysis,2000，21⑴：64-66。

32. Gang Li,Xinwen Guo,Xiangsheng Wang,et al.,Function of TPABr,n-butylamine and seeds in the synthesis of titanium silicalite,Journal of Fuel Chemistry and Technology (China),1999，27⑹，565-567。

33. Xiangsheng Wang,Xinwen Guo,Synthesis of titanium silicalites with cheap materials,Journal of Dalian University of Technology,2000，40⑵：155-159。

34. Yihua Zhang,Xinwen Guo,Xiangsheng Wang,et al.,Study on zeolite entrapped nano SnO2 clusters by CVD,Journal of Functional Materials (China),1999，30⑹，651-652.

35. Liqin Wang,Xiangsheng Wang,Xinwen Guo,Yihui Liu,Gang Li,Guimin Li,Effects of alcohol removal temperature in sol forming process on physicalchemical properties of titanium silicalites,Journal of Dalian University of Technology,2003,43 ⑷： 420-423.

36. Xinwen Guo,Xiangsheng Wang,Gang Li,Min Liu,Jinghai Xiu,Thermostability of titanium silicalites synthesized by cheap materials,Acta Petrolei Sinica (Petroleum Processing section),2002，18⑵：34-40.

37. Xinwen Guo,Min Liu,Xiangsheng Wang,Haisheng Yan,Gang Li,Characterization and epoxidation properties of titanium silicalite TS-1 with different crystal sizes,Acta Petrolei Sinica (Petroleum Processing section),2001，17⑹：16-23.

38. Xinwen Guo,Min Liu,Xiangsheng Wang,Gang Li,Yongying Chen,Song Liu,Effect of pretreatment methods on catalytic performance of titanium silicalite-1,Chinese Journal of Catalysis,2001,22⑷：370-372.

39. Xinwen Guo,Xiangsheng Wang,Gang Li,Fazhi Zhang,Zhuohua Zhang,Study on UV-Vis spectra of extra-framework titanium in titanium silicalites synthesized by different methods,Acta Petrolei Sinica (Petroleum Processing section),2001，17⑵：61-67.

40. Liqin Wang,Xiangsheng Wang,Xinwen Guo,et al.,Quick synthesis of titanium silicalite-1,Chinese Journal of Catalysis,2001,22⑹： 513-514.

41. Yihua Zhang,Xiangsheng Wang,Xinwen Guo,Development of titanium silicon catalytic materials I. Preparation of titania-silica mixed oxides and its catalytic properties,Prog Chem,2001,13⑴： 19-24.

42. Yihua Zhang,Xiangsheng Wang,Xinwen Guo,Development of titanium silicon catalytic materials I. Preparation of titanosilicate TS-1 and its physicochemical properties,Prog Chem,2001,13⑸： 382-391.

43. Yihua Zhang,Xiangsheng Wang,Xinwen Guo,Song Liu,Synthesis and Characterization of titanosilicalite and its Catalytic Performance,Chinese Journal of Catalysis,2001,22⑴： 92-94.

44. Ruipu Wang,Xinwen Guo,Xiangsheng Wang,Yihua Zhang,Study of styrene photocatalytic oxidation over TS-TiO2,Journal of Dalian University of Technology,2001，41⑶：288-291.

45. Fazhi Zhang,Xinwen Guo,Xiangsheng Wang,Development of large pore　titanium-containing molecular sieves,China Chemistry (Huaxue Tongbao),2000,2: 7-12.

46. Gang Li,Xiangsheng Wang,Xinwen Guo,Effects of the solvent,acid and base on the propylene epoxidation,Acta Petrolei Sinica (Petroleum Processing section),2001，17⑶：62.

47. Yihua Zhang,Xinwen Guo,Xiangsheng Wang,gang Li,Yongying Chen,Extraframework titanium species (TiO2）x in TS-1 zeolite and its effect on epoxidation of Propylene,Acta Petrolei Sinica (Petroleum Processing section),2000，16⑸：41-46.

48. Honglin Wang,Xinwen Guo,Xiangsheng Wang,et al.,Growing of nanostructured titanium-silicalite on amorphous titania and its catalytic activity in epoxidation,Chinese Journal of Catalysis,1999，20⑸：557-560.

49. Xinwen Guo,Xiangsheng Wang,Min Liu,Haisheng Yan,Yongying Chen,Jinghai Xiu,Study on the acid treatment of titanium silicalite TS-1,Chemical Journal of Chinese Universities,2000，21⑿，466.

50. Gang Li,Xinwen Guo,Xiangsheng Wang,Synthesis of TS-1 zeolite using tetra- propylammonium bromide as template,Acta Petrolei Sinica (Petroleum Processing section),1999，15⑴：90-93.

51. Ruipu Wang,Xinwen Guo,Xiangsheng Wang,Research Progress of propylene oxide synthesis by direct catalytic oxidation,Journal of Chemical Industry and Engineering (China),2003,54⑴： 2-8.

52. Haisheng Yan,Xiangsheng Wang,Jing Liu,Xinwen Guo,Study on the TS-1 deactivation during propylene epoxidation,Acta Petrolei Sinica (Petroleum Processing section),2002,18⑴：46.

53. Shaojie Guo,Yungan Ma,Jing Liu,Mingyue Zeng,Xinwen Guo,Xiangsheng Wang,Synthesis of 1,4-dioxane over modified Beta zeolite,Advances in Fine Petrochemicals (China),2003,4⑽： 24-26.

54. Jiwen Meng,Gang Li,Xiangsheng Wang,Xinwen Guo,Propylene epoxidation in nonprotic solvent,Journal of Dalian University of Technology,2003,43⑸： 577-581.

55. Xuewu Liu,Xiangsheng Wang,Ruipu Wang,Xinwen Guo,Gang Li,Study on the deactivated titanium silicalite during the epoxidation in the presence of N2,Journal of Molecular Catalysis (China),2003,17⑷： 247-254.

56. Gang Li,Xiangsheng Wang,Liqin Wang,Xinwen Guo,Comparison of two synthetic systems of titanium silicalite,Acta Petrolei Sinica (Petroleum Processing section),2003,19⑷： 76-81.

57. Jiwen Meng,Gang Li,Xiangsheng Wang,Xinwen Guo,Xuewu Liu,Effect of solvent on the propylene epoxidation catalyzed by TS-1,Journal of Molecular Catalysis (China),2003,17⑵： 106-110.

58. Guiru Wang,Bo Wang,Xiongfu Zhang,Yongzhong Wang,Hai-ou Liu,Xinwen Guo,Xiangsheng Wang,Characterization and Catalytic properties of Ti-Si-ZSM-5 zeolite with cheap materials,Journal of Dalian University of Technology,2000,40⑵： 160-164.

59. Yongzhong Wang,Guiru Wang,Xiongfu Zhang,Bo Wang,Hai-ou Liu,Xinwen Guo,Xiangsheng Wang,Influence of synthetic method on synthesis of Ti-Si-ZSM-5 zeolite and exploration of synthesis procedure,Journal of Dalian University of Technology,2000,40⑸： 540-545.

60. Xiangsheng Wang,Xinwen Guo,Liqin Wang,Quick synthesis of nano-scale TS-1 and its catalytic properties,Proceedings: 14th International zeolite conference. Editors: E. Van Steen et al. ISBN 0-958-46636-X,25-30 April 2004,Cape Town,South Africa,P2589-2595.

61. Weiguo Cheng,Xiangsheng Wang,Gang Li,Xinwen Guo,Bingjuan Du,Characterization and catalytic activity of hydrothermally treated TS-1/SiO2 in propylene epoxidation,Catalysis Letters,2004,95（3-4）： 185-190.

62. Gang Li,Jiwen Meng,Xiangsheng Wang,Xinwen Guo,Effect of solvents on propylene epoxidation catalyzed by titanium silicalite,React. Kinet. Catal. Lett.,2004,82⑴： 73-80.

63. Ruipu Wang,Xinwen Guo,Xiangsheng Wang,Research Progress of the heterogeneous photocatalytic oxidation,Huaxue Tongbao,2002,65,w037.

64. Min Liu,Xinwen Guo,Xiangsheng Wang,Highly effective phenol hydroxylation over Ti-ZSM-5 catalyst prepared using B-ZSM-5 as precursor,Chinese Journal of Catalysis,2004,25⑶： 169-170.

65. Yihua Zhang,Xinwen Guo,Xiangsheng Wang,et al.,Characterization and quantum size effect of Faujasite-supported dispersion of SnO2,Materials Science and Engineering,1999,17⑵： 23-25.

66. Xuewu Liu,Xiangsheng Wang,Xinwen Guo,Gang Li,Effects of propylene oxide on TS-1 catalytic performance during propylene epoxidation with hydrogen peroxide,ACTA PETROLEI SINICA (petroleum processing section),2003,19⑹： 29.

67. Junhong Zhang,Jing Liu,Xiangsheng Wang,Xinwen Guo,Technical Progress of green synthesis of propylene oxide,Henna Huagong,2003,1: 1-4.

68. Jiwen Meng,Gang Li,Xinwen Guo,Xiangsheng Wang,Integrated process of hydrogen peroxide and propylene oxide production,Modern Chemical Industry,2003,23⑿： 19.

69. Junhong Zhang,Jing Liu,Xiangsheng Wang,Yongchun Zhang,Xinwen Guo,Study on removal of trace water in propylene oxide with adsorption stripping,Applied Chemical Industry,2003,32⑷： 20-22.

70. Xuewu Liu,Xiangsheng Wang,Xinwen Guo,Gang Li,Study of propylene epoxidation catalyzed by TS-1 after recycling use,Journal of Dalian University of Technology,2004,44⑶： 356-361.

71. Qi Zhao,Xiuwen Han,Xiumei Liu,Runsheng Zhai,Liwu Lin，Ⅺnhe Bao,Xinwen Guo,Gang Li,Xiangsheng Wang,Studies on the process of Ti incorporation into the framework during the crystallization of TS-1 zeolite,Chinese Journal of Catalysis,1999,20⑴： 54-59.

Synthesis and Characterization of nano-scale molecular sieves

1. Weiping Zhang,Xinhe Bao,Xinwen Guo,Xiangsheng Wang,A high-resolution solid state NMR study on nano-structured HZSM-5 zeolites,Catal. Lett,1999,60 （1-2）： 89-94.

2. Weiping Zhang,Ding Ma,Xiuwen Han,Xinhe Bao,Xinwen Guo,Xaingsheng Wang,Methane dehydro-aromatization over Mo/ZSM-5 in the absence of oxygen: a multinuclear solid-state NMR study of the interaction between supported Mo species and HZSM-5 zeolite with different crystal sizes,J. of Catalysis,1999,188:393-402.

3. Weiping Zhang,Xiuwen Han,Xiumei Liu,Xinhe Bao,Xinwen Guo,Xaingsheng Wang,Thermostability of nanosized HZSM-5 zeolite,Chinese Journal of Catalysis,2000，21⑶：195-196。

4. Xinwen Guo,Yihui Liu,Xiangsheng Wang,Yongying Chen,Low temperature synthesis and characterization of ultra-fine ZSm-11 molecular sieves,Journal of Dalian University of Technology,2001，41⑷：426-430.

5. Lan Wang,Shuanghe Meng,Zhicheng Tan,Dongbai Liang,Xinwen Guo,Xiangsheng Wang,Study on thermostability of nanosized ZSM-5 zeolite,Chinese Journal of Catalysis,2001,22⑸： 491-493.

Others

1. Yunfeng Hu,Xiangsheng Wang,Xinwen Guo,Peng Xu,Silue Li,Hydroisomerization of n-octane over Pt/SAPO-41 catalyst,Chinese Journal of Catalysis,2004,25⑵： 87-88.

2. Jie Zhang,Huibo Shen,Dazhuang Liu,Lei Zhang,Xinwen Guo,Xiangsheng Wang,Steady-state activity in GPLE deactivation model,Journal of Chemical Engineering of Chinese Universities,1999,13⑴： 79-81.

3. Guohua Luo,Xin Xu,Zemin Tong,Xinwen Guo,Xiangsheng Wang,Removal of thiophene from coke-oven benzene by selective adsorption on zeolites,Journal of Fuel chemistry and technology,1999,27⑸： 476-480.

4. Dazhuang Liu,Lei Zhang,Xinwen Guo,Xiangsheng Wang,Experiment Design of GPLE Deactivation kinetics Model,Journal of Zhengzhou University of Technology,1999,20⑴： 4-6.

5. Guohua Luo,Guoying Zhang,Xinwen Guo,Xin Xu,Zemin Tong,Xiangsheng Wang,Desulfurization reaction of thiophene in Benzene with methanol and ethanol on zeolite molecule sieves,Journal of Petrochemical Universities,2000,13⑴： 24-27.

6. Jianqin Zhuang,Jingmei Yin,Dabin Gao,Xuefang Zheng,Guangyun Zhou,Ningzhang Zhou,Xiangsheng Wang,Xinwen Guo,Studies on the Carbonylation of carbon Dioxide under single wavelength Visible light Irradiation,Chemical Journal of Chinese Universities,2001,22⑴： 75-77.

2002年獲中國石油和化學工業協會科技進步一等獎（部級，即原昊華獎，排名3）。2003年獲國家科技進步二等獎（排名3）。2004年入選遼寧省百千萬人才工程百人層次，2005年入選新世紀優秀人才支持計劃，2006年獲得遼寧省第五屆青年科技獎， 2007年被評為大連市第四批優秀專家。